CAS 101-31-5 MFCD00067306-L-Hyoscyamine 莨菪碱 TAO{mole}

L-Hyoscyamine 莨菪碱

CAS 101-31-5 MFCD00067306

化学结构图

SMILES: CN1[C@H]2CC[C@@H]1C[C@H](OC(=O)[C@H](CO)c1ccccc1)C2

化学属性

Mol. Formula	C17H23NO3
Mol. Weight	289.37
Appearance	白色结晶性粉末，无臭，苦辣味。易消旋，水溶液呈碱性。Mp108.5℃，比旋光度[α] D 20 powder -21°(乙醇)。本品极易溶于乙醇和稀酸，易溶于氯仿(1：1)，可溶于水(1：280)、乙醚(1：69)和苯(1：159)。
Melting Point	108.5 °C
Boiling Point	429.804 °C at 760 mmHg

别名和识别编码

Chemical Name	L-Hyoscyamine
MDL Number	MFCD00067306
CAS Number	101-31-5
Synonym	L-Hyoscyamine {LY} L-Hyoscyamine {} {LY} L-Hyoscyamine {} {} {LY} L-Hyoscyamine {} {} {} {LY} L-Hyoscyamine {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {} {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {} {} {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Hyoscyamine {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number	202-933-0
Reaxys-RN	91259
Merck Number	4858
Beilstein Registry Number	91259
PubChem Substance ID	154417
Chemical Name Translation	莨菪碱
Wiswesser Line Notation	T56 A ANTJ A1 GOVYR&1Q -L
LabNetwork Molecule ID	LN00365394
InChI	InChI=1S/C17H23NO3/c1-18-13-7-8-14(18)10-15(9-13)21-17(20)16(11-19)12-5-3-2-4-6-12/h2-6,13-16,19H,7-11H2,1H3/t13-,14+,15?,16-/m1/s1
Canonical SMILES	CN1[C@@H]2C[C@@H](OC([C@@H](C3=CC=CC=C3)CO)=O)C[C@H]1CC2

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

RTECSNH0875000

WGK Germany3

Safety Statements

S24 Avoid contact with skin 避免皮肤接触；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Hazard Codes 6.1 T+

Risk Statements

R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒

UN Number 1544 UN 1544 6.1/PG 2

Signal word Danger

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P301+P310+P330
P304+P340+P310
P307+P311
P308+P311
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H300+H330

Packing GroupII

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

Hazard Class6.1

GHS Symbol

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 1471 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DCAI "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M.,
   Springfield, IL, C.C. Thomas, 1970  Volume(issue)/page/year: 2,73,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 95 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   BJPCAL British Journal of Pharmacology and Chemotherapy.  (London, UK)
   V.1-33, 1946-68.  For publisher information, see BJPCBM.
   Volume(issue)/page/year: 24,138,1965

其他信息

Sigma Aldrich:101-31-5(sigmaaldrich)
下游产品:硫酸阿托品
TCI Shanghai:(-)-莨菪碱 (-)-Hyoscyamine,>;99.0%(T)(101-31-5)
用途一:生化研究，抗胆碱药及检测金的试剂。
MOL 文件:101-31-5.mol
color:white
上游原料:颠茄浸膏
方法一:颠茄浸膏经提取精制而得。
L-天仙子胺价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 H0450 (-)-莨菪碱 (-)-Hyoscyamine 5G 1020元 2014/06/02 H0450 (-)-莨菪碱 (-)-Hyoscyamine 25G 3010元
参考质量标准:mp105-107℃，比旋光度-19°-21°，灼烧残渣≤0.1%。
图谱信息:L-天仙子胺(101-31-5)核磁图( 13 CNMR) L-天仙子胺(101-31-5)质谱(MS) L-天仙子胺(101-31-5)Raman光谱 L-天仙子胺(101-31-5)红外图谱(IR1) L-天仙子胺(101-31-5)核磁图( 1 HNMR)