Bis(8-quinolinolato)copper(II) 8-羟基喹啉铜

CAS 10380-28-6 MFCD00067392

化学结构图

10380-28-6
SMILES: C1=CC=C2C=CC=NC2=C1O[Cu]OC1=CC=CC2=CC=CN=C21

化学属性

Mol. FormulaC18H12CuN2O2
Mol. Weight351.85
Melting Point240 °C (dec.)(lit.)

别名和识别编码

Chemical NameBis(8-quinolinolato)copper(II)
Synonym Bis(8-oxyquinoline)copper Cellu-quin Copper hydroxyquinolinate Oxime copper Copper-8 Copper 8-quinolate Milmer Oxyquinolinoleate de cuivre Copper oxyquinolate Bis(quinolin-8-olato)copper Copper 8-quinolinol Copper 8-hydroxyquinoline Cunilate 2472 Cupric 8-hydroxyquinolate Copper (2+) oxinate Bis(8-quinolinato)copper 8-羟基喹啉 铜(II) 盐 Copper quinolinolate Copper oxine Quinondo Bis(8-quinolinolato)copper Cupric 8-quinolinolate Copper, bis(8-quinolinolato-N(sup 1),O(sup 8))- Dokirin Cupric 8-hydroxyquinolate; 8-Hydroxyquinoline copper complex; Bis(8-quinolinolato)copper; Oxine-copper Fruitdo Copper 8-quinolinolate Cunilate Copper oxyquinoline oxine-copper Copper oxinate Oxine copper Bioquin 1 Oxine cuivre Copper 8-hydroxyquinolate Copper quinolate 8-Hydroxyquinoline copper complex Copper 8-hydroxyquinolinate Kupfer-8-hydroxychinolin
MDL NumberMFCD00067392
PubChem Substance ID87564578
CAS Number10380-28-6
EC Number233-841-9
Reaxys-RN3918032
Chemical Name Translation8-羟基喹啉铜
Wiswesser Line NotationT66 BNJ JO 2-CU-
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分类

  • {SNA} Materials Science, Metal Complex Dopants and Dyes, Organic and Printed Electronics, Photoluminescent Materials, Photonic and Optical Materials
  • {uni_hamburg} no charge; oxygen heterocycle; nitrogen heterocycle; other heterocycle; carbocycle; aromatic; large ring; fused rings; 5ring; 6ring; 9ring; 10ring; 11ring; 1fragment
  • {SNA} Metal Complex Dopants and Dyes, Organic and Printed Electronics, Photoluminescent Materials, Photonic and Optical Materials, 材料科学

相关文献及参考

  • Short: IV/4 Title: High-Pressure Properties of Matter Author: Beggerow, G. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/4 Year: 1980 ISBN: 3-540-09370-2 ISBN: 978-3-540-09370-1 Internet Resource: DOI:10.1007/b90280 RefComment: 589 figs., VIII, 427 pages. Hardcover Abstract: The main topics are pressure dependences of phase equilibria, compressibility, thermal and caloric properties, transport phenomena, static and magnetic properties, optical phenomena, kinetic phenomena, and systems in the neighbourhood and above the critical area.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P308+P311
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P305+P351+P338+P337+P313
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P309+P311
  • P337+P313
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Hazard Codes Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
RTECSVC5250000
Packing GroupIII
UN Number 3077
Hazard Class9
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 156 mg/kg/39W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   24,109,1960

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 67 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   5,599,1963

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3940 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USS

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 820 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NNGADV Nippon Noyaku Gakkaishi.  Journal of the Pesticide Science Society of
   J

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 22 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NNGADV Nippon Noyaku Gakkaishi.  Journal of the Pesticide Science Society of
   Japan.  (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170,
   Japan)  V.1-    1976-  Volume(issue)/page/year: 16,563,1991

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 116,185,1983

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