CAS 142-59-6 MFCD00069382-Nabam TAO{mole} - 淘摩尔专家级采购助手

Nabam

CAS 142-59-6 MFCD00069382

化学结构图

SMILES: [Na]SC(=S)NCCNC(=S)S[Na]

化学属性

Mol. Formula	C4H6N2Na2S4?xH2O
Mol. Weight	256
Solubility	溶于水。

别名和识别编码

Chemical Name	Carbamic acid, ethylenebis(dithio-, disodium salt
Synonym	那班 N,N'-Ethylene bis(dithiocarbamate de sodium) NABAM 1,2-ethanediylbis-carbamodithioicacidisodiumsalt Ethylenebis(dithiocarbamate), disodium salt Dinatrium-(N,N'-aethylen-bis(dithiocarbamat)) chem-bam Nabam 代森钠 1,2-联二乙基氨基甲酰二硫酸二钠 DITHANE S(R) disodium1,2-ethanediylbis(carbamodithioate) Parzate liquid Spring-bak chembam dithanea-40 CHEM BAM(R) dinatrium-(n,n’-aethylen-bis(dithiocarbamat)) 1,2-ethanediylbiscarbamodithioicaciddisodiumsalt Chem BAM DSE Nabame 1,2-Ethanediylbiscarbamodithioic acid disodium salt Dinatrium-(N,N'-ethyleen-bis(dithiocarbamaat)) Di-natrium-aethylenbisdithiocarbamat Carbamodithioicacid,1,2-ethanediylbis-,disodiumsalt Dithane A-40 di-natrium-aethylenbisdithiocarbamat Ethylenebis(dithiocarbamic acid) disodium salt Carbamodithioic acid, 1,2-ethanediylbis-, disodium salt N,N'-Etilen-bis(ditiocarbammato) di sodio 伸乙雙(二硫胺甲酸鈉) Disodium ethylene-1,2-bisdithiocarbamate Disodium ethylenebis(dithiocarbamate) Dithane D-14 D-14(R) PARZATE LIQUID(R) carbond Ethylen-bis-dithiokarbaman sodny Nafun IPO 乙撑双二硫代氨基甲酸钠 Disodium ethylene-1，2-bis-dithiocarbamate Parzate dinatrium-(n,n’-ethyleen-bis(dithiocarbamaat)) dithaned-14(discontinued) DISODIUM ETHYLENE BIS[DITHIOCARBAMATE] Nabasan
MDL Number	MFCD00069382
PubChem Substance ID	24869095
EC Number	205-547-0
Chemical Name Translation
CAS Number	142-59-6
Merck Number	13,6367
Wiswesser Line Notation	SUYSHM2MYUS&SH &-NA- 2

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安全信息

RTECSFA6825000

GHS Symbol

Precautionary statements

P501 Dispose of contents/container to..… 处理内容物/容器.....
P273 Avoid release to the environment. 避免释放到环境中。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。

Hazard statements

H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H302 Harmful if swallowed 吞食有害
H335 May cause respiratory irritation 可能导致呼吸道刺激

WGK Germany3

Signal word Warning

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Safety Statements

S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
S8 Keep container dry 保持容器干燥；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Hazard Codes Xn,N

Risk Statements

R37 Irritating to respiratory system 刺激呼吸道
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
R22 Harmful if swallowed 吞咽有害
R50/53
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Storage condition 0-6°C

UN Number UN3077 9/PG 3

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 395 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FEPRA7 Federation Proceedings, Federation of American Societies for
   Experimental Biology. (Bethesda, MD)  V.1-46, 1942-87.
   Volume(issue)/page/year: 11,391,1952

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 580 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCOC** Pesticide Chemicals Official Compendium, Association of the American
   Pesticide Control Officials, Inc., 1966.  (Topeka, KS)
   Volume(issue)/page/year: -,777,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel,"
   Perkow, W., Berlin, Verlag Paul Parey, 1971-1976  Volume(issue)/page/year:
   -,-,1971/1976

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 1000 ppm
REFERENCE :
   MMAPAP Mycopathologia et Mycologia Applicata.  (The Hague, Netherlands)
   V.5-54(4), 1950-74.  For publisher information, see MYCPAH.
   Volume(issue)/page/year: 50,233,1973

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 418 mg/kg
SEX/DURATION            : female 6-14 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-160

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 194 mg/kg
SEX/DURATION            : female 6-14 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - extra-embryonic structures
   (e.g., placenta, umbilical cord)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-160

其他信息

MOL 文件:142-59-6.mol
用途:代森钠即亚乙基双二硫代氨基甲酸二钠，是杀菌剂代森锌、代森锰锌等的重要中间体。
RTECS号:FA6825000
生产方法:其制备方法是在反应釜中预先加入清水，在搅拌下加入乙二胺，控制反应温度小于35℃开始滴加二硫化碳，滴加完毕，保持反应物料温度在30℃左右继续搅拌30min，待反应物料的介质pH≤9时，开始分批向反应釜加入20%氢氧化钠水溶液，加碱时反应温度控制在35℃左右，每批加氢氧化钠后控制反应液的pH≤9后，才能加下一批氢氧化钠。在全部氢氧化钠加完后，继续保温反应1h，取样观察物料中已无明显油珠即为达到反应终点，降温至25℃以下，停止搅拌，静置，将未反应的二硫化碳分离出来，所得淡黄色液体即为代森钠水溶液。代森钠的合成有一步法和两步法，国内均采用两步法，此法有利于控制副产物三硫代碳酸钠的生成，因此产品质量好，收率亦高。
外观性质:有硫样臭味的琥珀样固体。