CAS 280-64-8 MFCD00074742-9-Borabicyclo[3.3.1]nonane 9-硼双环[3.3.1]壬烷 TAO{mole}

9-Borabicyclo[3.3.1]nonane 9-硼双环[3.3.1]壬烷

CAS 280-64-8 MFCD00074742

化学结构图

SMILES: B1C2CCCC1CCC2

化学属性

Mol. Formula	C8H15B
Mol. Weight	122.02
Density	0.894
Boiling Point	68-70 °C
Flash Point	-19°(-2°F)
Solubility	起反应
TSCA	No
Stability	对空气和水分敏感
Danger-Level	甲类
pH	:A

别名和识别编码

Chemical Name	9-Borabicyclo[3.3.1]nonane
CAS Number	280-64-8
EC Number	206-000-9
Beilstein Registry Number	605509
MDL Number	MFCD00074742
Synonym	9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {} {
PubChem Substance ID	6327450
Chemical Name Translation	9-硼双环[3.3.1]壬烷
InChIKey	FEJUGLKDZJDVFY-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00222630
InChI	InChI=1S/C8H14B/c1-3-7-5-2-6-8(4-1)9-7/h7-8H,1-6H2
Canonical SMILES	C1(B2)CCCC2CCC1

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品牌质保精细包装现货库存一流品牌服务

产品应用

使用 9-BBN 对相应环状缩醛进行还原以鉴别对称二醇。
选择性硼氢化还原试剂。
Reactant for:
• Linear SPPS synthesis of ubiquitin derivatives
• Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides
• Intramolecular insertion of alkenes into palladium-nitrogen bonds
• Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast
• Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S30 Never add water to this product 切勿将水加入该产品中；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；

Risk Statements

R11 Highly flammable 非常易燃
R14 Reacts violently with water 遇水会猛烈反应
R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
R19 May form explosive peroxides 可能生成易爆的过氧化物质
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R38 Irritating to skin 刺激皮肤
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R48/20
R51/53
R62 Possible risk of impaired fertility 有削弱生殖能力的危险
R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P222 Do not allow contact with air. 不要与空气接触。
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
P231+P232
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P330+P331
P302+P334
P303+P361+P353
P304+P340
P305+P351+P338
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P331 Do NOT induce vomiting.. 不要催吐。
P335+P334
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P402+P404
P403+P235
P405 Store locked up. 上锁保管。
P422 Store contents under… 存储目录在…之下。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
H351 Suspected of causing cancer 怀疑致癌
H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 4.3 F,Xn F,Xn,N F,Xn,Xi,N F;Xi

UN Number 3399

Packing GroupI

Storage condition 2-8°C {LY} 2-8°C Flammables area {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

HazardClass:4.1
9-硼双环[3.3.1]壬烷价格(试剂级):更新日期产品编号产品名称包装价格 2010/06/21 165818000 9-硼双环[3.3.1]壬烷 9-Borabicyclo[3.3.1]nonane , 0.5M solution in THF, AcroSeal® 800 ML 2077元 2010/06/21 165811000 9-硼双环[3.3.1]壬烷 9-Borabicyclo[3.3.1]nonane , 0.5M solution in THF, AcroSeal® 100 ML 523元
MOL 文件:280-64-8.mol
PackingGroup:III
F:1-10-34