Ethynylmagnesium bromide 乙炔基溴化镁
CAS 4301-14-8 MFCD00075342
化学结构图
SMILES: C#C[Mg]Br
化学属性
| Mol. Formula | C2HMgBr |
|---|---|
| Mol. Weight | 129.24 |
| Density | 0.94 |
别名和识别编码
| Chemical Name | Ethynylmagnesium bromide |
|---|---|
| CAS Number | 4301-14-8 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 3600874 |
| MDL Number | MFCD00075342 |
| PubChem Substance ID | 4071243 |
| Synonym | Ethynyl magnesium bromide,0.5M solution in THF,Safeseal {LY} Ethynyl magnesium bromide,0.5M solution in THF,Safeseal {} {LY} Ethynyl magnesium bromide,0.5M solution in THF,Safeseal {} {} {LY} Ethynyl magnesium bromide,0.5M solution in THF,Safeseal {} {} {} {LY} Ethynyl magnesium bromide,0.5M solution in THF,Safeseal {} {} {} {} {LY} Ethynyl magnesium bromide,0.5M solution in THF,Safeseal {} {} {} {} {} {LY} Ethynyl magnesium bromide,0.5M solution in THF,Safeseal {} {} {} {} {} {} {LY} Ethynyl magnesium bromide,0.5M solution in THF,Safeseal {} {} {} {} {} {} {} {LY} Ethynyl magnesium bromide,0.5M solution in THF,Safeseal {} {} {} {} {} {} {} {} {LY} Ethynyl magnesium bromide,0.5M solution in THF,Safeseal {} {} {} {} {} {} {} {} {} {LY} Ethynyl magnesium bromide,0.5M solution in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {LY} Ethynyl magnesium bromide,0.5M solution in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {} {LY} Ethynyl magnesium bromide,0.5M solution in THF,Safe |
| Chemical Name Translation | 乙炔基溴化镁 |
| LabNetwork Molecule ID | LN01314287 |
| InChI | InChI=1S/C2H.BrH.Mg/c1-2;;/h1H;1H;/q-1;;+2/p-1 |
| Canonical SMILES | C#C[Mg]Br |
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分类
- {SNA} Alkynyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
相关文献及参考
安全信息
GHS Symbol
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- R11 Highly flammable 非常易燃
- R14 Reacts violently with water 遇水会猛烈反应
- R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R22 Harmful if swallowed 吞咽有害
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R37 Irritating to respiratory system 刺激呼吸道
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P231+P232
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P370+P378
- P402+P404
- P403+P235
- P422 Store contents under… 存储目录在…之下。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H302 Harmful if swallowed 吞食有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H351 Suspected of causing cancer 怀疑致癌
- H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
