1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dicarboxylic anhydride 1,4,5,6,7,7-六氯-5-降冰片烯-2,3-二甲酸酐
CAS 115-27-5 MFCD00080438
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信息真实价格透明
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分类
- {SNA} Alicyclic/Etch-Resistant Monomers, Curing Agents for Epoxides, Lithography Monomers, Micro/NanoElectronics, Polymer Additives, Polymer Science, Self Assembly & Contact Printing, 材料科学
- {SA} Alicyclic/Etch-Resistant Monomers, Crosslinking Agents and Additives for Epoxides, Lithography Monomers, Materials Science,
相关文献及参考
- Aldrich MSDS 1 , 1014:D / Corp MSDS 1 (1), 1835:B / FT-IR 2 (1), 1217:D / FT-IR 1 (1), 720:A / FT-NMR 1 (1), 1182:C / IR-Spectra (3), 420:G / IR-Spectra (2), 372:B / RegBook 1 (1), 839:C / Structure Index 1 , 130:A:5
- Beil. 17 ,IV,6070
- Merck 14 ,2086
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H351 Suspected of causing cancer 怀疑致癌
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
- H303 May be harmfully swallowed 吞食可能有害
- P304+P340+P312
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P332+P313
- P273 Avoid release to the environment. 避免释放到环境中。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
- P305+P351+P338+P337+P313
- P403+P233
- P405 Store locked up. 上锁保管。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P302+P352+P333+P313+P362+P364
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S25 Avoid contact with eyes 避免眼睛接触;
- R45 May cause cancer 可能致癌
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R51/53
- R48/20/21/22
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R52/53
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 2300 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 26(4),49,1982
其他信息
- 灭火剂:水,二氧化碳, 泡沫, 干粉
- 可燃性危险特性:热分解排出有毒氯化物烟雾
- 类别:有毒物质
- 氯桥酸酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0349 氯桥酸酐 Het Anhydride 500G 578元 2014/06/02 H0349 氯桥酸酐 Het Anhydride 25G 150元 2010/06/21 146950010 氯桥酸酐 1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dicarboxylic anhydride 96% 1 KG 1084元
- Acros Organics:氯茵酸酐 1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dicarboxylic anhydride, 96%(115-27-5)
- 图谱信息:氯桥酸酐(115-27-5)核磁图( 1 HNMR) 氯桥酸酐(115-27-5)核磁图( 13 CNMR) 氯桥酸酐(115-27-5)红外图谱(IR3) 氯桥酸酐(115-27-5)红外图谱(IR1) 氯桥酸酐(115-27-5)红外图谱(IR2)
- Sigma Aldrich:115-27-5(sigmaaldrich)
- 急性毒性:口服-大鼠 LD50: 2300 毫克/公斤; 口服-小鼠 LD50: 2400 毫克/公斤
- 毒性分级:中毒
- 方法一:由六氯环戊二烯与顺酐反应而得。将六氯环戊二烯与顺酐按1:1.1的摩尔比混合在溶剂氯苯中,在140-145℃反应7-8h后,将反应产物加入水中水解,在70℃时水解得到的氯桥酸成为油状液体,加热到96-97℃时与水混溶,冷却后成为含一结晶水的氯桥酸(Het acid[115-28-6])。若反应产物用热水及稀乙酸进行结晶,一水合物经100-105℃干燥,即得氯桥酸酐。
- 上游原料:六氯环戊二烯 --> 氯菌酸
- MOL 文件:115-27-5.mol
- Alfa Aesar:<=3% Chlorendic anhydride, 96%, may cont. up to 3% chlorendic acid(115-27-5)" href="http://www.alfa.com/zh/GP100w.pgm?DSSTK=L07349&CAS;=115-27-5">氯菌酸酐,96%,氯菌酸<=3% Chlorendic anhydride, 96%, may cont. up to 3% chlorendic acid(115-27-5)
- 蒸气密度:13 (vs air)
- 刺激数据:眼睛-兔 100 毫克 重度
- 储运特性:库房低温通风干燥
- 用途二:氯桥酸酐和氯桥酸都是反应型阻燃剂,适用于不饱和聚酯、聚氨酯和环氧树脂,也用作环氧树脂固化剂。由该品固化的环氧树脂制品的热变形温度约180℃,耐药性好,氯桥酸也作为染料中间体和杀虫剂。也用作织物的阻燃剂。
- TCI Shanghai:氯桥酸酐 Het Anhydride,>;95.0%(T)(115-27-5)
- 用途一:用作环氧树脂和聚氨酯的反应型阻燃剂
- 敏感性:Moisture Sensitive