Polyphosphoric acid 多聚磷酸
CAS 8017-16-1 MFCD00084480
化学结构图
SMILES: O=P(O)(O)O.o1op2oop1o2
化学属性
| Density | 2.05 |
|---|---|
| TSCA | Yes |
| Mol. Formula | H3O9P3 |
| Boiling Point | |
| Solubility | MAY DECOMPOSE |
| Mol. Weight | 240 |
| Stability | 易吸潮 |
| Melting Point | No Data Available |
别名和识别编码
| MDL Number | MFCD00084480 |
|---|---|
| EC Number | 232-417-0 |
| CAS Number | 8017-16-1 |
| Merck Number | 14,7580 |
| Synonym | Concise etchant Condact K-etchant POLYPHOSPHORIC ACID POLYPHOSPHORIC ACID REAGENT GRADE 115& POLYPHOSPHORIC ACID , 84% MIN. POLYPHOSPHORIC ACID FOR SYNTHESIS PPA Phosphoric acids, super- or poly- Polyphosphoic Acid Polyphosphoric Acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
| Chemical Name | Polyphosphoric acid |
| Chemical Name Translation | 多聚磷酸 |
| PubChem Substance ID | 73357664 |
| InChI | InChI=1S/O5P2.H3O4P/c1-2-7-4-3-6(1)5-7;1-5(2,3)4/h;(H3,1,2,3,4) |
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信息真实价格透明
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分类
- {SNA} Chemical Synthesis, Inorganic Acids, Synthetic Reagents
- {SNA} Acids, Acids & Bases, Chemical Synthesis, Inorganic Acids, Synthetic Reagents
- {SNA} Acids, Acids & Bases, Alternative Energy, Analytical Reagents for General Use, Battery Electrolyte Materials, Chemical Synthesis, Electrolytes, Enabling Products, Greener Alternative Products, Inorganic Acids, Material Sciences, Reagent Grade Acids & Bases, Synthetic Reagents, 分析/色谱, 分析试剂, 材料科学
- {uni_hamburg} no charge; polymer; 1fragment
产品应用
- 主要用作分析试剂，并可作为有机合成的闭环缩合剂(化学环化剂)和酰化剂。
相关文献及参考
- Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as a supplement to volume II/1 of the 6th Edition, which contains only a few data on nonaqueous systems. Data are not listed for all systems but primarily for those of greater interest where data for a larger range of concentrations were available.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
- Promotes the rearrangement of 1-arylindoles to 5H-dibenzo[b,f]azepines: Tetrahedron, 51, 2091 (1995).
安全信息
GHS Symbol
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P301+P330+P331
- P302+P361+P354
- P303+P361+P353
- P304+P312
- P304+P340
- P305+P351+P338
- P305+P354+P338
- P307+P311
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P316
- P317
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P403+P233
- P404 Store in a closed container. 贮存于密闭容器中。
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H290 May be corrosive to metals 可能腐蚀金属。
- H302 Harmful if swallowed 吞食有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H318 Causes serious eye damage 严重伤害眼睛
其他信息
- 外观性质:无色粘稠状液体，易潮解。
- 多聚磷酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80104528 多聚磷酸 500ml 28.3元 2010/06/21 196950010 多聚磷酸 Polyphosphoric acid , pure, >; 84% phosphate (as P2O5) 6 x 1 KG 3564元 2010/06/21 196950010 多聚磷酸 Polyphosphoric acid , pure, >; 84% phosphate (as P2O5) 1 KG 594元
- 60℃易流动，低温时凝固似玻璃。易吸湿潮解，不结晶，有腐蚀性，能与水混溶水解为正磷酸，有腐蚀性。
- 下游产品:5-氨基吲哚 --> 2-(3-氯-4-氟苯基)吲哚 --> 3-(三氟甲基)-5,6,7,8-四氢-[1,2,4]三唑并[4,3-a]吡嗪盐酸盐 --> 齐拉西酮 --> 2,2-二苯基-1-苦味基肼自由基 --> 2-羟甲基-5-溴-1H-吲哚 --> 焦磷酸 --> 3-(4-联苯基)-1,2,3,4-四氢-1-萘酚 --> 5-氯吲哚-2-羧酸 --> 三聚磷酸钾 --> 4-(1H-吲哚-2-基)苯胺 --> 4-溴-2-三氟甲基喹啉 --> 5-溴吲哚-2-羧酸 --> 3-甲基-1H-吡唑并[3,4-B]吡啶 --> 6-溴-4-二氢色原酮 --> 2-(三氟甲基)喹啉-4-醇 --> 5-溴吲哚-2-羧酸乙酯 --> 3-三氟甲基-1,2,4-三唑并[4,3-a]吡嗪 --> 5-氯吲哚-2-羧酸乙酯 --> 7-溴异喹啉 --> 2,5-二(4-氨基苯基)噁二唑 --> 液晶杂环高聚物 --> T-49型固体磷酸催化剂 --> W-331新型阻垢缓蚀剂 --> 2-(4-氟苯基)吲哚 --> 西替普塔林 --> NJ-213缓慢阻垢剂 --> SH-1缓蚀剂 --> WT-302-1预膜剂 --> JS-204预膜缓蚀剂 --> 淀粉磷酸酯钠 --> JC-861清洗预膜剂 --> 扎托布洛芬
- EPA Substance Registry System:8017-16-1(EPA Substance)
- 方法一:合成法将磷酸和五氧化二磷加热进行聚合反应，加入双氧水除去溶液中的铁离子，经净化后，冷却、过滤，制得多磷酸成品。其 2H3PO4+P2O5→H6P4O13
- 用途二:用于有机合成，也用作正磷酸的代用品
- 用途四:主要用作分析试剂，并可作为有机合成的闭环缩合剂(化学环化剂)和酰化剂。
- 用途一:有机合成中用作环化剂和酰化剂，也是正磷酸的代用品
- 敏感性:Hygroscopic
- 毒害物质数据:8017-16-1(Hazardous Substances Data)
- Alfa Aesar:聚磷酸,ca84%(asphosphoruspentoxide) Polyphosphoric acid, ca 84% (as phosphorus pentoxide)(8017-16-1)
- 检测方法:T
- 用途三:在有机合成中用作化合物环化剂及酰化剂。也用作正磷酸的代用品及分析试剂。
- 海关编码:28092000
- 上游原料:磷酸
