Carbophenothion -

CAS 786-19-6 MFCD00128009

化学结构图

786-19-6
SMILES: CCOP(=S)(OCC)SCSC1C=CC(Cl)=CC=1

化学属性

Mol. FormulaC₁₁H₁₆ClO₂PS₃
Mol. Weight342.87
Flash Point-
Solubility不溶于水,溶于苯、甲苯、醇、酮。
Density0.7915
Boiling Point-

别名和识别编码

Chemical NameCarbophenothion
CAS Number786-19-6
Synonym ######## Acarithion Akarithion CARBOPHENOTHION Carbofenothion Carbofenthion Carbophenothion {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {hazard_com} O,O-Diethyl p-chlorophenylmercaptomethyl dithiophosphate {} {} {} {} {} {} {} {hazard_com} O,O-Diethyl dithiophosphoric acid p-chlorophenylthiomethyl ester {} {} {} {} {} {} {} {} {hazard_com} O,O-Diethyl S-p-chlorophenylthiomethyl dithiophosphate {} {} {} {} {} {} {} {} {} {hazard_com} O,O-Diethyl S-(p-chlorophenylt {} {} {} {} {} {} {} {} {} {} {hazard_com} O,O-Diethyl S-(4-chlorophenylthiomethyl) dithiophosphate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {hazard_com} O,O-Diaethyl-S-((4-chlor-phenyl-thio)-methyl)dithiophosphat {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} O,O-DIETHYL-S-[P-CHLOROPHENYLTHIO]-METHYL PHOSPHORODITHIOATE {}
MDL Number-
PubChem Substance ID24868746
Beilstein Registry Number1885240
EC Number212-324-1
Chemical Name Translation-
Merck Number13,1831
Wiswesser Line Notation2OPS&O2&SR D1SPS&O2&O2
Canonical SMILES-
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Aromatics
  • Phosphorylating and Phosphitylating Agents
  • Sulfur & Selenium Compounds
  • {SNA} Acaricides, Alphabetic, Analytical Standards, Analytical/Chromatography, C, CA - CG, Chromatography, Environmental Standards, Insecticides, Organophorous, Pesticides & Metabolites, Pesticides Standards

产品应用

  • Carbophenothion is an organophosphorus pesticide used for fruits and vegetables.

相关文献及参考

  • Scott, G., et al.: J. Agric. Food Chem., 50, 4400 (2002),
  • Mezcua, M., et al.: Food Chem., 112, 221 (2009),
  • Mezcua, M., et al.: Anal. Chem., 81, 913 (2009),

安全信息

RTECSTD5250000
GHS Symbol
Precautionary statements
  • P301+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
WGK Germany3
Signal word Danger
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
Hazard Codes T,N T,N,Xn,F
Risk Statements
  • R11 Highly flammable 非常易燃
  • R38 Irritating to skin 刺激皮肤
  • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
  • R50/53
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Storage condition -20°C, Hygroscopic APPROX 4°C 储存温度2-8℃
UN Number 3018
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - pigeon
DOSE/DURATION           : 34800 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PSSCBG Pesticide Science.  (Blackwell Scientific Pub. Ltd., POB 88, Oxford,
   UK)  V.1-    1970-  Volume(issue)/page/year: 6,245,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - chicken
DOSE/DURATION           : 57200 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - spastic paralysis with or without sensory
   change
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - ataxia
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   11,,49,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 27 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PSEBAA Proceedings of the Society for Experimental Biology and Medicine.
   (Academic Press, Inc., 1 E. First St., Duluth, MN 55802)  V.1-    1903/04-
   Volume(issue)/page/year: 129,699,1968

TYPE OF TEST            : LD50 - Lethal dose

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 5600 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   21,31

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 20 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 102,89,1982

其他信息

  • 用途:三硫磷为优良的有机磷杀虫、杀螨剂,普遍应用于棉花、果树等作物,防治红蜘蛛、蚜虫等多种害虫。
  • 杀虫剂单一组分标准液
  • HazardClass:6.1(a)
  • PackingGroup:II
  • MOL 文件:786-19-6.mol
  • 生产方法:以氯苯、五硫化二磷、甲醛、乙醇、氯磺酸为主要原料,经下述步骤生产得三硫磷原油。1.对氯苯磺酰氯的制备将氯磺酸加入反应锅,滴加氯苯,反应所得物料为对氯苯磺酰氯和氯磺酸、硫酸的混合物(磺化液)。2.对氯硫酚的制备反应锅中加入水,用蒸气预热到回流,再加入铁粉搅拌下滴加上述磺化液得对氯硫酚。3.对氯苯氯代甲硫醚的制备反应锅中,加入的浓盐酸在搅拌下加入甲醛滴加对氯硫酚的苯溶液得对氯苯氯代甲硫醚。4.硫化物钠盐的制备向五硫化二磷中滴加无水乙醇,将反应物,滴加到碳酸氢钠的水溶液中,得到硫化物钠盐水溶液。5.三硫磷的制备将上述硫化物钠盐水溶液加入反应锅,滴加对氯苯氯代甲硫醚。静置分层,取油层,用水洗涤,干燥即得三硫磷原油。
  • 外观性质:灰白色至琥珀色、微有硫醇气味的液体。
  • RTECS号:TD5250000

系列性分类


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