Terbutryn 特丁净

CAS 886-50-0 MFCD00128025

化学结构图

886-50-0
SMILES: CCNc1nc(NC(C)(C)C)nc(SC)n1

化学属性

Mol. FormulaC10H19N5S
Mol. Weight241
Melting Point104-105 ºC
Boiling Point154-160 ºC
Density1.45
Solubility0.0025 G/100 ML
Flash Point2 °C
Appearance Pa (20℃)。易溶于异丙醇、二甲苯等有机溶剂，20℃时在水中溶解度为58mg/L。正常条件下性质稳定，无腐蚀性。 -3 本品为白色粉末。m.p.104～105℃，蒸气压0.128×10

别名和识别编码

Chemical NameTerbutryn
CAS Number886-50-0
Synonym ######## 1,3,5-Triazine-2,4-diamine, 1,3,5-Triazine-2,4-diamine, N-(1,1-dimethylethyl)-N'-ethyl-6-(methylthio)- 2-(tert-butylamino)-4-(ethylamino)-6-(methylthio)-s-triazin 2-(tert-butylamino)-4-(ethylamino)-6-(methylthio)-s-triazine 2-Methylthio-4-ethylamino-6-tert-butylamino-s-triazine 2-TERT-BUTYLAMINO-4-ETHYLAMINO-6-METHYL-THIO-S-TRIAZINE 2-TERT-BUTYLAMINO-4-ETHYLAMINO-6-METHYLTHIO-1,3,5-TRIAZINE 2-Tert.-butylamino-4-ethylamino-6-methylthio-[1,3,5]triazin 2-ethylamino-6-methylthio-4-tert-butylamino-1,3, 5-triazine 2-tert-Butylamino-4-ethylamino-6-methylmercapto-s-triazine 2-tert-Butylamino-4-ethylamino-6-methylthi 2-tert-Butylamino-4-ethylamino-6-methylthio-1,3,5-triazine; 2-(tert-Butylamino)-4-(ethylamino)-6-(methylthio)-s-triazine; N-(1,1-dimethylethyl)-N'-ethyl-6-(methylthio)-1,3,5-triazine-2,4-diamine
MDL NumberMFCD00128025
PubChem Substance ID13450
Beilstein Registry Number0611817
EC Number212-950-5
Chemical Name Translation特丁净
Wiswesser Line NotationT6N CN ENJ BS1 DMX1&1&1 FM2
InChIInChI=1S/C10H19N5S/c1-6-11-7-12-8(15-10(2,3)4)14-9(13-7)16-5/h6H2,1-5H3,(H2,11,12,13,14,15)
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分类

  • {Chemicalbook} 农药: 除草剂: 有机杂环类除草剂
  • {SNA} Alphabetical Index of Analytical Standards, Analytical
  • {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Herbicides, Pesticides & Metabolites, Q-Z, T, TA - TE, Triazines
  • {SA} Alpha sort,
  • {SNA} Analytical Standards, Q-Z, Triazines, 农残和代谢标准品, 分析/色谱, 按照字母排序, 灭草剂
  • {SNA} All Herbicide Standards, Analytic
  • Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography,

产品应用

  • A triazine herbicide.

相关文献及参考

  • Campanella, L., et al.: Water Res., 35, 69
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSXY4725000
GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P352
  • P305+P351+P338
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P333+P313
  • P337+P313
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
Hazard Codes F,Xn Xi,N,Xn,F Xi,N
WGK Germany2
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Gloves
Signal word Danger Warning
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R50/53
  • R11 Highly flammable 非常易燃
Storage condition APPROX 4°C 室温储存 储存温度2-8℃
UN Number UN 3077 9/PG 3 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >10200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CIGET* Ciba-Geigy Toxicology Data/Indexes.  (Ciba-Geigy Corp., 556 Morris
   Ave., Summit, NJ 07901)  Volume(issue)/page/year: -,-,1977

{hazar

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 2900 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,438,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2045 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PESTD5 Proceedings of the European Society of Toxicology.  (Amsterdam,
   Netherlands)  V.16-18, 1975-77.  Discontinued.  Volume(issue)/page/year:
   17,351,1976

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >8 gm/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A384,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - chicken
DOSE/

其他信息

  • MSDS 信息:2-tert-Butylamino-4-ethylamino-6-methylthio-1,3,5-triazine(886-50-0).msds
  • 储运特性:库房通风低温干燥
  • 类别:农药
  • 毒性分级:中毒
  • MOL 文件:886-50-0.mol
  • 用途二:均三氮苯类除草剂，具有内吸性传导作用。属选择性芽前和芽后除草剂。可用于冬小麦、大麦、高梁、向日葵、花生、大豆、豌豆、马铃薯等作物田，防除多年生裸麦草、黑麦草及秋季萌发的繁缕、母菊、罂粟、看麦娘、马唐、狗尾草等。用于冬小麦、大麦使用剂量20～25g有效成分/100m 2 ，芽后用于玉米为10g有效成分/100m 2 。
  • 杀虫剂单一组分标准液
  • 急性毒性:口服- 大鼠 LD50: 2045 毫克/ 公斤; 口服- 小鼠 LD50: 3884 毫克/ 公斤
  • 上游原料:三聚氯氰 --> 叔丁胺 --> 甲硫醇,压力包装,约为22克。 --> 1,3,5-三嗪
  • 用途一:属内吸传导型除草剂，可用于芽前、芽后除草
  • 毒性:大鼠急性经口LD 50 2400～2980mg/kg，小鼠为5000mg/kg。大鼠和狗亚慢性毒性试验无作用剂量分别为每天50mg/kg和40mg/kg。对鸟低毒，母鸡LD 50 4000mg/kg。对鱼为中等毒性。
  • 可燃性危险特性:燃烧产生有毒硫氧化物和氮氧化物气体
  • 灭火剂:干粉、泡沫、砂土
  • 方法一:三聚氯氰与特丁胺作用生成2，4-二氯-6-特丁氨基-1，3，5-三嗪；然后与乙胺作用生成2-氯-4-乙氨基-6-特丁氨基-1，3，5-三嗪，最后与甲硫醇反应生成特丁净。
  • 用途三:内吸传导型除草剂，可用于芽前、芽后除草，土壤中持效期3-10周。主要用于冬小麦、大麦、高粱、向日葵、马铃薯、豌豆、大豆、花生等作物田，防除多年生裸麦草、黑麦草及秋季萌发的繁缕、母菊、罂粟、看麦娘、马唐、狗尾草等。
  • 刺激数据:皮肤- 兔子 380 毫克 轻度; 眼睛- 兔子 76 毫克 中度
  • Sigma Aldrich:886-50-0(sigmaaldrich)

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Alpha sort - Pesticides & Metabolites
  7. Q-Z - Alpha sort
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TA - TE - T
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TA - TE - T

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