Amylopectin From Maize 支链淀粉

CAS 9037-22-3 MFCD00130510

化学结构图

9037-22-3
SMILES: OCC1OC(OC2C(CO)OC(OCC3OC(OC4C(CO)OC(O)C(O)C4O)C(O)C(O)C3OC3OC(CO)C(O)C(O)C3O)C(O)C2O)C(O)C(O)C1O

化学属性

Mol. Formula(C6H10O5)n
Mol. Weight828.72
Stability易吸潮

别名和识别编码

MDL NumberMFCD00130510
CAS Number9037-22-3
EC Number232-911-6
PubChem Substance ID87562080
Merck Number481
Synonym Amylopectin from maize Amylopectin from potato starch 支链淀粉 胶淀粉
Chemical NameAmylopectin From Maize
Chemical Name Translation支链淀粉
InChIInChI=1S/C30H52O26/c31-1-6-11(35)13(37)19(43)28(50-6)55-24-9(4-34)52-27(21(45)16(24)40)48-5-10-25(56-29-20(44)14(38)12(36)7(2-32)51-29)17(41)22(46)30(53-10)54-23-8(3-33)49-26(47)18(42)15(23)39/h6-47H,1-5H2/t6-,7-,8-,9-,10-,11-,12-,13+,14+,15-,16-,17-,18-,19-,20-,21-,22-,23-,24-,25-,26+,27+,28-,29-,30-/m1/s1
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分类

  • {SNA} Biochemicals and Reagents, Carbohydrates, Carbohydrates A to Z, Carbohydrates A-C, Cell Biology, Fiber and Prebiotics, Functional Foods, Nutrition Research, Polysaccharide, Soluble Fiber, Including Prebiotics
  • {SNA} Biochemicals and Reagents, Carbohydrates, Carbohydrates A to Z, Carbohydrates A-C, Fiber and Prebiotics, Functional Foods, Nutrition Research, Polysaccharide, Soluble Fiber, Including Prebiotics, 细胞生物学
  • Biochemicals and Reagents, Carbohydrates, Carbohydrates A to Z, Carbohydrates A-C, Fiber and Prebiotics,
  • {SNA} Carbohydrates A to Z,

产品应用

  • Amylopectin is a glucose-based, highly-branched polysaccharide which together with amylose makes starch. The glucosidic bonds of amylopectin are α-1,4 in the glucan chain and α-1,6 at the branch points. Amylopectin from maize differs in structure form amylopectin from other plant species and is used in the study of the development of starches.

相关文献及参考

  • Lin Q, Huang B, Zhang M, et al., Functional interactions between starch synthase III and isoamylase-type starch debranching enzyme in maize endosperm. Plant Physiol. 158(2) , 679-92, (2011)
  • Dhital S, Shrestha AK, Hasjim J, Gidley MJ., Physicochemical and structural properties of maize and potato starches as a function of granule size. J. Agric. Food Chem. 59 , 10151-10161, (2011)
  • Johnston DA, Mukerjea R, Robyt JF., Preparation and characterization of new and improved soluble-starches, -amylose, and -amylopectin by reaction with benzaldehyde/zinc chloride. Carbohydr. Res. 346 , 2777-2784, (2011)
  • Zhu F, Corke H, Åman P, Bertoft E., Structures of building blocks in clusters of sweetpotato amylopectin. Carbohydr. Res. 346 , 2913-2924, (2011)
  • Juna S, Huber A., Effect of varying flow regimes upon elution behaviour, apparent molecular characteristics and hydrodynamic properties of amylopectin isolated from normal corn starch using asymmetrical flow field-flow fractionation. J. Chromatogr. A. 1219 , 161-172, (2012)
  • Merck 14 ,481

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

其他信息

  • 支链淀粉白色粉状,又称胶淀粉。支链淀粉是以优质糯玉米为原料生产的一种纯天然支链淀粉。与普通淀粉相比具有较高的膨胀性、粘滞性和透明度,其膨胀性是普通淀粉的2.7倍。普通淀粉溶液很不稳定,贮存时逐渐变成混浊,胶粘性降低,最后出现白色结晶沉淀。而支链淀粉很容易溶于水生成稳定的溶液,且具有很强的粘度,不易发生老化,淀粉液在贮存过程中,不发生沉淀。
  • 支链淀粉白色粉状,又称胶淀粉。支链淀粉是以优质糯玉米为原料生产的一种纯天然支链淀粉。与普通淀粉相比具有较高的膨胀性、粘滞性和透明度,其膨胀性是普通淀粉的2.7倍。普通淀粉溶液很不稳定,贮存时逐渐变成混浊,胶粘性降低,最后出现白色结晶沉淀。而支链淀粉很容易溶于水生成稳定的溶液,且具有很强的粘度,不易发生老化,淀粉液在贮存过程中,不发生沉淀。 支链淀粉是一个具有树枝形分支结构的多糖。相对分子质量较大,一般由1000-300,000个左右葡萄糖单位组成,分子量约为100万,有些可达600万。D-吡喃葡萄糖单位通过α-1,4-苷键连接成一直链,此直链上又可通过α-1,6-苷键形成侧链,在侧链上又会出现另一个分支侧链。主链中每隔6-9个葡萄糖残基就有一个分支,每一个支链平均含有约15-18个葡萄糖残基,平均每24-30个葡萄糖残基中就有一个非还原尾基。因此支链淀粉的结构为高支化聚合物,十分复杂。

系列性分类


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