N-Methoxy-N-Methyl(Triphenylphosphoranylidene)Acetamide N-甲氧基-N-甲基(三苯基正膦亚基)乙酰胺
CAS 129986-67-0 MFCD00134433
化学结构图
SMILES: CON(C)C(=O)C=P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | C22H22NO2P |
|---|---|
| Mol. Weight | 363 |
| Melting Point | 173-175 °C(lit.) |
别名和识别编码
| Chemical Name | N-Methoxy-N-Methyl(Triphenylphosphoranylidene)Acetamide |
|---|---|
| Synonym | N-甲氧基-N-甲基(三苯基正膦亚基)乙酰胺 (N-甲氧基甲基氨基羰基亚甲基)三苯基正膦 |
| Beilstein Registry Number | 4198472 |
| PubChem Substance ID | 24863472 |
| CAS Number | 129986-67-0 |
| MDL Number | MFCD00134433 |
| Chemical Name Translation | N-甲氧基-N-甲基(三苯基正膦亚基)乙酰胺 |
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- 1. Fang, F.; et al. Eur. J. Org. Chem. , 1084, (2011)
- 2. Sinisi, R.; et al. Proc. Natl. Acad. Sci. U. S. A. 107 , 20652, (2010)
- 3. Aroyan, C. E.; et al. J. Org. Chem. 75 , 5784, (2010)
- 4. Farwick, A.; Helmchen, G. Adv. Synth. Catal. 352 , 1023, (2010)
- 5. Calo, F.; et al. Org. Lett. 11 , 4910, (2009)
- FT-NMR 1 (2), 1681:A / RegBook 1 (2), 2281:K / Structure Index 1 , 357:C:5
安全信息
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
