4,5-Dimethoxy-2-Nitrobenzyl Carbonochloridate 4,5-二甲氧基-2-硝基苄基氯甲酸酯

CAS 42855-00-5 MFCD00143507

化学结构图

42855-00-5
SMILES: COC1=CC(COC(=O)Cl)=C(C=C1OC)[N+]([O-])=O

化学属性

Mol. FormulaC10H10ClNO6
Mol. Weight276
Melting Point125 °C (dec.) (lit.)
TSCANo

别名和识别编码

Chemical Name4,5-Dimethoxy-2-Nitrobenzyl Carbonochloridate
CAS Number42855-00-5
Alfabeta NameDIMETHOXYNITROBENZYLCARBONOCHLORIDATE 452---,
MDL NumberMFCD00143507
Synonym NVOC-Cl Chloroformic acid 6-nitroveratryl ester 6-硝基藜芦基氯甲酸酯 NVOC 氯化物 4,5-二甲氧基-2-硝基苄基氯甲酸酯 6-硝基藜芦氯甲酸 6-硝基藜芦基氯甲酸酯 6-硝基藜芦氯甲酸 NVOC 氯化物 NVOC-Cl
Beilstein Registry Number2389168
PubChem Substance ID24866307
Chemical Name Translation4,5-二甲氧基-2-硝基苄基氯甲酸酯
InChIKeyRWWPKIOWBQFXEE-UHFFFAOYSA-N
LabNetwork Molecule IDLN00135712
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分类

  • {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry,

相关文献及参考

  • FT-IR 2 (2), 2960:D / Structure Index 1 , 318:A:7
  • Reagent for protection of amines. The group is readily cleaved photolytically: Tetrahedron Lett., 29, 65 (1988). For use in N-protection of bases in nucleotide synthesis, see: J. Org. Chem., 64, 6319 (1999). For reviews of photochemical protecting groups in organic synthesis, see: Synthesis, 1 (1980); Org. Photochem., 9, 225 (1987).

安全信息

Warnings IRRITANT-HARMFUL, CORROSIVE
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
WGK Germany3
GHS Symbol
Signal word Danger
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Hazard Codes C
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
UN Number UN3261
Risk Statements
  • R37 Irritating to respiratory system 刺激呼吸道
  • R34 Causes burns 会导致灼伤
Storage condition Moisture & Light Sensitive

系列性分类


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