(S)-(-)-2-Acetoxypropionylchloride (S)-(-)-2-乙酰氧基丙酰氯
CAS 36394-75-9 MFCD00145252
化学结构图
SMILES: CC(=O)O[C@@H](C)C(=O)Cl
化学属性
| Mol. Formula | C5 |
|---|---|
| Mol. Weight | 151 |
| Refractive index | 1.4190 to 1.4230 |
| Boiling Point | 78°C/22mmHg(lit.) |
| Density | 1.189 g/mL at 25 °C(lit.) |
别名和识别编码
| Chemical Name | (S)-(-)-2-Acetoxypropionylchloride |
|---|---|
| Synonym | |
| CAS Number | 36394-75-9 |
| PubChem Substance ID | 87562758 |
| Beilstein Registry Number | 1722943 |
| MDL Number | MFCD00145252 |
| Reaxys-RN | 4305993 |
| Chemical Name Translation | (S)-(-)-2-乙酰氧基丙酰氯 |
| EC Number | 420-610-4 |
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信息真实价格透明
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分类
- {SNA} Acid Halides, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
- {SNA} Alcohols, Analytical Reagents, Analytical/Chromatography, Chiral Derivatization Reagents, Chiral GC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents GC, GC Derivatization Reagents, by Application, Reagents for Acylation
- Acid Halides, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
相关文献及参考
- 1. Zhu, J. et al. J. Org. Chem. 60 , 6389, (1995)
- 2. Kende, A.S. et al. J. Am. Chem. Soc. 115 , 9842, (1993)
- 3. Burlina, F. et al. Tetrahedron Lett. 35 , 8151, (1994)
- 4. Hulst, R. et al. Tetrahedron 50 , 11721, (1994)
- 5. Tetrahedron Asymmetry 2 , 987, (1991)
- Beil. 3 ,II,189
- FT-IR 2 (1), 1250:C
安全信息
GHS Symbol
- H290 May be corrosive to metals 可能腐蚀金属。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H302 Harmful if swallowed 吞食有害
- P303+P361+P353+P310+P363
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P405 Store locked up. 上锁保管。
- P304+P340
- P303+P361+P353
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P304+P340+P310
- P301+P330+P331+P310
- P234 Keep only in original container. 只保留在原来的容器中。
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- R34 Causes burns 会导致灼伤
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R22 Harmful if swallowed 吞咽有害
