Barium hydroxide octahydrate 氢氧化钡 八水合物

CAS 12230-71-6 MFCD00149152

化学结构图

12230-71-6
SMILES: O.O.O.O.O.O.O.O.O[Ba]O

化学属性

Mol. FormulaBaH18O10
Mol. Weight315.46
Melting Point78
Density2.18
SolubilitySoluble in water, methanol. Slightly soluble in ethanol. Practically insoluble in acetone
TSCAYes

别名和识别编码

Chemical NameBarium hydroxide octahydrate
MDL NumberMFCD00149152
PubChem Substance ID24891652
CAS Number12230-71-6
EC Number241-234-5
Merck Number14,977
Synonym Ba (OH)2 · 8H2O Bariumhydroxid-8-hydrat 氢氧化钡 Barium hydroxide, octahydrate 氢氧化钡(八水) Bariumhydroxid-Octahydrat Barium hydroxide octahydrate Bariumhydroxid Octahydrat Bariumoxidhydrat-Octahydrat Ätzbaryt Barium hydroxide (Ba(OH)2), octahydrate 氢氧化钡 八水合物
Chemical Name Translation氢氧化钡 八水合物
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分类

  • {SNA} Acids & Bases, Bases, Chemical Synthesis, Inorganic Bases, Synthetic Reagents
  • Chemical Synthesis, Dephosphorylation Reagent, Inorganic Bases, Phosphorylation Analysis, Post-Translational Modification, Protein Modification, Protein Structural Analysis, Proteomics, Reagents and Controls for Phosphoprotein Analysis, Synthetic Reagents
  • {SNA} Chemical Synthesis, Inorganic Bases, Synthetic Reagents
  • {uni_hamburg} no charge; 11fragments; ionic

产品应用

  • 测定空气中的二氧化碳,精制糖及动物油,锅炉用水清洗剂。

相关文献及参考

  • Short: III/31a
  • For a brief feature on uses of the reagent, see: Synlett, 1739 (2002).
  • Merck: 14,977
  • Suzuki coupling of 4-iodopyridines with arylboronic acids is promoted by this base which has advantages for sterically hindered substrates: J. Organomet. Chem., 517, 25 (1996).
  • Preferred base for the Horner-Wadsworth-Emmons reaction with sensitive aldehydes, such as in formation of complex (E)-enones in natural product synthesis: Synlett, 774 (1993).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
Hazard Codes 8 C
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
RTECSCQ9200000
Safety Statements
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
UN Number 3262 UN3262
Risk Statements
  • R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
Storage condition Air Sensitive & Hygroscopic 密封干燥保存。 Air Sensitive
Packing GroupIII

其他信息

  • 强碱性,易溶于水及甲醇,微溶于乙醇,不溶于丙酮。从空气中吸收二氧化碳变成碳酸盐后,则不能完全溶于水。在硫酸干燥器中能失去7分子结晶水,约在780℃失去全部结晶水。
  • 易溶于水及甲醇,微溶于乙醇,不溶于丙酮。从空气中吸收二氧化碳变成碳酸盐后,则不能完全溶于水。在硫酸干燥器中能失去7分子结晶水,约在780℃失去全部结晶水。

系列性分类


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