Bismuth Nitrate Pentahydrate 硝酸铋(III)五水合物
CAS 10035-06-0 MFCD00149157
化学结构图
SMILES: O.O.O.O.O.[Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
化学属性
| Mol. Formula | Bi(NO3)3·5H2O |
|---|---|
| Mol. Weight | 485 |
| Boiling Point | 80 |
| Melting Point | 30 |
| Density | 2.83 |
| TSCA | Yes |
| Solubility | 溶于稀硝酸、乙醇、丙酮。 |
| Stability | 易吸潮 |
别名和识别编码
| Chemical Name | Bismuth Nitrate Pentahydrate |
|---|---|
| MDL Number | MFCD00149157 |
| PubChem Substance ID | 24870440 |
| EC Number | 233-791-8 |
| Synonym | Bismuth trinitrate pentahydrate 五水合硝酸铋 三硝酸铋 硝酸铋 硝酸铋(III) 五水合物 三硝酸铋，五水硝酸铋 五水硝酸铋 Bismuth(III) nitrate pentahydrate |
| CAS Number | 10035-06-0 |
| Merck Number | 14,1271 |
| Chemical Name Translation | 硝酸铋(III)五水合物 |
| LabNetwork Molecule ID | LN00196631 |
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分类
- {SNA} Bismuth, Bismuth Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, 材料科学
- {SNA} ACS Grade, Bismuth, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Inorganic Salts, Solutions and Reagents, Research Essentials
- {SNA} Bismuth, Catalysis and Inorganic Chemistry, Chemical Synthesis
产品应用
- 沉淀生物碱，钠、铷和铯的试剂，原子吸收光谱标准制备。制造其他铋盐。一种优良的氧化剂，用于各种4-取代的Hantzsch 1,4-dihydropyridines。sufides 转换成sulfoxides的选择性氧化剂。
相关文献及参考
- Useful, easily handled oxidizing and nitrating agent in organic synthesis. Montmorillonite KSF acidic clay impregnated with bismuth nitrate was found to be an excellent reagent for high-yield aromatic nitration: Tetrahedron Lett., 41, 8017 (2000). Phenols can be nitrated with the salt itself in acetone, or without solvent: J. Org. Chem., 70, 9071 (2005). In the presence of montmorillonite, alcohols can be oxidized to carbonyl compounds: Synth. Commun., 31, 2691 (2001). Reagent for deprotection of oximes: Synthesis, 1010 (2001), and hydrazones: Synth. Commun., 32, 1917 (2001). Thioamides and thioureas are readily converted to their oxo-analogs: Tetrahedron Lett., 44, 591 (2003).
- Catalyst for a convenient, high-yield Michael addition of various substrates, including amines, imidazoles and indoles, to enones: J. Org. Chem., 68, 2109 (2003). Efficient catayst for tetrahydropyranylation and depyranylation of alcohols: Eur. J. Org. Chem., 4891 (2005).
- For a brief feature on uses of the reagent in organic synthesis, see: Synlett, 2699 (2005).
- Merck:14,1271
安全信息
GHS Symbol
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P305+P351+P338
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
- H319 Causes serious eye irritation 严重刺激眼睛
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S17 Keep away from combustible material 远离可燃物料；
- R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- 有硝酸气味。易吸潮，呈酸性反应。于75-80度失去全部结晶水，在水中分解成碱式盐。能溶于稀硝酸、甘油、丙酮、稀酸（包括乙酸），几乎不溶于乙醇和乙酸乙酯。
- 各种 4-位取代-1,4-二氢吡啶汉斯酯的优良氧化剂。将硫化物选择性氧化成亚砜的简便试剂。
