Nickel(II) Nitrate Hexahydrate 硝酸镍(II)六水合物(易制爆)

CAS 13478-00-7 MFCD00149805

化学结构图

13478-00-7
SMILES: O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Ni+2]

化学属性

Mol. FormulaNi(NO3)2· 6H2O
Mol. Weight290.79
Density2.05 g/mL at 25 °C(lit.)
Melting Point56 °C(lit.)
SolubilitySoluble in water, alcohol
TSCAYes
Boiling Point137
Flash Point137°C
Stability对湿度敏感

别名和识别编码

Chemical NameNickel(II) Nitrate Hexahydrate
CAS Number13478-00-7
PubChem Substance ID61630
EC Number236-068-5
MDL NumberMFCD00149805
Merck Number14,6513
Synonym 硝酸镍(II) 六水合物 硝酸镍
Chemical Name Translation硝酸镍(II)六水合物(易制爆)
InChIKeyAOPCKOPZYFFEDA-UHFFFAOYSA-N
InChIInChI=1S/2NO3.Ni.6H2O/c2*2-1(3)4;;;;;;;/h;;;6*1H2/q2*-1;+2;;;;;;
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分类

  • {SNA} Materials Science, Metal and Ceramic Science, Ni, Nickel Salts, Salts, Ultra-High Purity Materials
  • {SA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, I-N, Puriss p.a., Puriss p.a.
  • {SNA} Essential Chemicals, Metal and Ceramic Science, Ni, Nickel Salts, Research Essentials, Salts, Ultra-High Purity Materials, 材料科学

产品应用

  • 用于镀镍、金属着色、镍催化剂、陶瓷褐色颜料、化学试剂等。

相关文献及参考

  • Merck: 14,6513

安全信息

GHS Symbol
WGK Germany3
Hazard Codes O,T O,T,N
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H350 May cause cancer 可能致癌
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H302+H332
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSQR7300000
Precautionary statements
  • P305+P351+P338
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
Signal word Danger
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Packing GroupIII
UN Number
Risk Statements
  • R38 Irritating to skin 刺激皮肤
  • R49 May cause cancer by inhalation 吸入会致癌
  • R42/43
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R48/23
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
  • R50/53
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Storage condition 密封干燥保存 Hygroscopic

其他信息

  • 易溶于水、液氧、氨水、乙醇中,微溶于丙酮,水溶液呈酸性,PH值约为4。有吸湿性,潮湿空气中很快潮解。干燥空气中缓慢风化,受热时会失去四个分子水,温度高于110℃时开始分解并形成碱式盐,继续加热生成棕黑色的三氧化二镍和绿色的氧化亚镍的混合物。接触尘沫及其他有机物,有时能引起燃烧或爆炸。

系列性分类


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