Ruthenium(III)Chloride Hydrate 三氯化钌(III)水合物
CAS 14898-67-0 MFCD00149844
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {S
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Ru Ca
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis,
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Hematology Stains, Hematology and Histology,
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Ru Catalysts, Ruthenium Catalysts
- {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Ru Catalysts, Ruthenium, Ruthenium Salts, Salts
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Ru Catalysts,
产品应用
- 1.多相催化或均相催化
- 2.电镀、电解阳极
- 与氧化剂发生氧化反应的催化剂
相关文献及参考
- In the presence of NaOH, is a catalyst for the high-yield rearrangement of sec-allylic alcohols to saturated ketones: J. Chem. Soc., Chem. Commun., 594 (1980). In MeOH, allyl alcohols are converted to allyl ethers. The thermodynamically more stable isomer predominates: Synth. Commun., 12, 807 (1982):
- Merck 14 ,8302
- Used catalytically, in the presence of a suitable reoxidant, such as periodate or sometimes hypochlorite, RuCl3 is a source of the powerful oxidizing agent, ruthenium(VIII) oxide, RuO4: J. Org. Chem., 46, 3936 (1981); J. Am. Chem. Soc., 103, 464 (1981).
- Oxidations by RuO4 include: Alkenes to carboxylic acids: J. Am. Chem. Soc., 103, 464 (1981); Org. Synth. Coll., 8, 377 (1993). In biphasic solvent systems, the reaction can also be controlled to give good yields of syn-diols: Angew. Chem. Int. Ed., 33, 2312 (1994); Chem. Eur. J., 2, 50 (1996). For an improved protocol, employing only 0.5 mol% catalyst, see: Org. Lett., 5, 3353 (2003). For oxidation of diols to carboxylic acids: J. Org. Chem., 53, 5185 (1988). `,a-Enones to carboxylic acids: J. Org. Chem., 52, 689 (1987). Alkynes to `-diketones: Helv. Chim. Acta, 71, 237 (1988). Ethers to esters: Tetrahedron Lett., 24, 3829 (1983). Amines to amides: Chem. Pharm. Bull., 36, 3125 (1988). Methylbenzenes to benzoic acids: J. Org. Chem., 51, 2880 (1986). For the oxidation of alkenes, al
- For a brief survey of uses of RuC3 in Organic synthesis, see: Synlett, 1974 (2007).
- In the presence of 2,2'-bipyridine, catalyzes the stereospecific epoxidation of alkenes. The configuration of the alkene is retained: Tetrahedron Lett., 25, 3187 (1984).
- Oxidations by RuO4 include: Alkenes to carboxylic acids: J. Am. Chem. Soc., 103, 464 (1981); Org. Synth. Coll., 8, 377 (1993). In biphasic solvent systems, the reaction can also be controlled to give good yields of syn-diols: Angew. Chem. Int. Ed., 33, 2312 (1994); Chem. Eur. J., 2, 50 (1996). For an improved protocol, emplo
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- R34 Causes burns 会导致灼伤
其他信息
- 外观性质:为带有光泽的晶体颗粒,一般呈灰褐色或暗红色,有腐蚀性,极易潮解,溶于水、醇、丙酮和乙酸乙酯中中,在热水中分解。
- Sigma Aldrich:14898-67-0(sigmaaldrich)
- Alfa Aesar:氯化钌(III)水合物,Premion|r,99.99%(metalsbasis) Ruthenium(III) chloride hydrate, Premion, 99.99% (metals basis)(14898-67-0)
- 用途二:1.多相催化或均相催化2.电镀、电解阳极3.电子工业等重要化工原料
- 用途一:用作干燥剂、吸附剂、催化剂载体
- 下游产品:2-(3-溴-6-甲基-2-吡嗪酮-1(2H)-基)乙酸乙酯 --> 2-(3,4-二氢-6-甲基-2,3-二氧代吡嗪-1(2H)-基)乙酸乙酯 --> 三苯基膦氯化钌 --> 环辛二烯二氯化钌(II) --> 三联吡啶氯化钌六水合物
- Acros Organics:三氯化钌水合物 Ruthenium(III) chloride hydrate, 35 - 40% Ru(14898-67-0)
- 三氯化钌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 51022021 水合三氯化钌 1g 150元 2010/06/21 195480250 三氯化钌 Ruthenium(III) chloride hydrate , 35 - 40% Ru 25 GR 3628元 2010/06/21 195480010 三氯化钌 Ruthenium(III) chloride hydrate , 35 - 40% Ru 1 GR 311元
- 敏感性:Hygroscopic
- 一般呈灰褐色或暗红色,有腐蚀性,极易潮解,溶于水、醇、丙酮和乙酸乙酯中中,在热水中分解。
- MOL 文件:14898-67-0.mol