Tri(2-furyl)phosphine 三(2-呋喃基)膦
CAS 5518-52-5 MFCD00151857
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资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
- Aromatics
- Heterocycles
- Chelating Agents & Ligands,
- {uni_hamburg} no charge; oxygen heterocycle; aromatic; 5ring; 1fragment
产品应用
- 磷化氢配体,用于过渡金属介入的有机合成; 也用于Wittig 反应。
相关文献及参考
- In a study of Pd-catalyzed coupling reactions in supercritical CO 2, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, L06941.
- Best ligand for Pd-catalyzed coupling of 5-iodouracil and unsaturated tributylstannanes: Synlett, 157 (1991).
- Short: III/35C4
- Beilstein:18(5)12,505
- Large rate enhancements (10 2 -10 3 ) over triphenylphosphine are observed in Pd-catalyzed coupling of olefinic stannanes and electrophiles: J. Am. Chem. Soc ., 113, 9585 (1991).
- Andersen N.G. et al.: Chem. Rev., 101, 997 (2001); Appel M. et al.: Eur. J. Org. Chem., 1143, (2002);
安全信息
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P350
- P302+P352
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P319
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P362+P364
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- TCI Shanghai:三(2-呋喃基)膦 Tri(2-furyl)phosphine,>;96.0%(GC)(5518-52-5)
- F:10-23
- Sigma Aldrich:5518-52-5(sigmaaldrich)
- 用途一:磷化氢配体,用于过渡金属介入的有机合成; 也用于Wittig 反应。
- MOL 文件:5518-52-5.mol
- Acros Organics:三(2-呋喃基)磷 Tri-(2-furyl)phosphine, 98%(5518-52-5)
- color:faintly brown
- 三(2-呋喃)磷化氢价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1643 三(2-呋喃基)膦 Tri(2-furyl)phosphine 5G 2150元 2014/06/02 T1643 三(2-呋喃基)膦 Tri(2-furyl)phosphine 1G 697元 2010/06/21 294802500 三(2-呋喃)磷化氢 Tri-(2-furyl)phosphine 98% 250 MG 492元
- Alfa Aesar:三(2-呋喃基)膦,97% Tri(2-furyl)phosphine, 97%(5518-52-5)