[(1R)-(endo,anti)]-(+)-3-Bromocamphor-8-sulfonic acid ammonium salt [(1R)-(内型,反式)]-(+)-3-溴樟脑-8-磺酸铵盐

CAS 14575-84-9 MFCD00167438

化学结构图

14575-84-9
SMILES: C[C@]12CC[C@H]([C@H](Br)C1=O)[C@@]2(C)CS(=O)(=O)O.N

化学属性

Mol. FormulaC10H18BrNO4S
Mol. Weight328
Melting Point284
TSCANo
Solubility200 G/L (25 ºC)
Density1.422

别名和识别编码

Chemical Name[(1R)-(endo,anti)]-(+)-3-Bromocamphor-8-sulfonic acid ammonium salt
CAS Number14575-84-9
Synonym (1S,2S,4R,7R)-2-Bromo-4,7-dimethyl-3-oxo-bicyclo[2.2.1]heptane-7-methanesulfonic Acid Ammonium Salt [(1R)-endo,anti]-3-Bromo-1,7-dimethyl-2-oxo-bicyclo[2.2.1]heptane-7-methanesulfonic acid ammonium salt; D(+)-alpha-Bromocamphor-pi-sulfonic acid ammonium salt [(1R)-(内型,反式)]-(+)-3-溴樟脑-8-磺酸 铵盐 [1S-(endo,anti)]-3-Bromo-1,7-dimethyl-2-oxo-bicyclo[2.2.1] Ammonium (+)-3-Bromo-8-camphorsulfonate
MDL NumberMFCD00167438
PubChem Substance ID87564068
EC Number238-616-9
Beilstein Registry Number11,319
Chemical Name Translation[(1R)-(内型,反式)]-(+)-3-溴樟脑-8-磺酸铵盐
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Sulfonic/Sulfinic Acid Salts
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Sulfonic/Sulfinic Acid Salts

产品应用

  • Bromocamphor solutions use in optically resolutions.

相关文献及参考

  • Beil. 11 ,319
  • Corp MSDS 1 (1), 511:C / FT-IR 2 (1), 1518:A / FT-IR 1 (1), 897:B / FT-NMR 1 (1), 1437:A / IR-Spectra (2), 477:F / IR-Spectra (3), 539:H / NMR-Reference 2 (2), 798:C / RegBook 1 (1), 1063:M / Structure Index 1 , 165:C:8
  • Elliott, M.C.

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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