(1R,3S,4S,7R)-3-Bromo-7-(Bromomethyl)-1,7-Dimethylbicyclo[2.2.1]Heptan-2-One (1R,3S,4S,7R)-3-溴-7-(溴甲基)-1,7-二甲基双环[2.2.1]庚烷-2-酮

CAS 10293-10-4 MFCD00167983

化学结构图

10293-10-4
SMILES: C[C@]12CC[C@H]([C@H](Br)C1=O)C2(C)CBr

化学属性

Mol. FormulaC10H14Br2O
Mol. Weight310.03
Melting Point156-159 °C(lit.)

别名和识别编码

Chemical Name(1R,3S,4S,7R)-3-Bromo-7-(Bromomethyl)-1,7-Dimethylbicyclo[2.2.1]Heptan-2-One
Synonym 3,9-二溴-(+)-樟脑 (+)-3,9-二溴茨酮
MDL NumberMFCD00167983
PubChem Substance ID87569123
CAS Number10293-10-4
Reaxys-RN2258438
Beilstein Registry Number7,127
Chemical Name Translation(1R,3S,4S,7R)-3-溴-7-(溴甲基)-1,7-二甲基双环[2.2.1]庚烷-2-酮
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Ketones, Organic Building Blocks
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Ketones, Organic Building Blocks

相关文献及参考

  • Beil. 7 ,127
  • Corp MSDS 1 (1), 1074:C / FT-IR 2 (1), 685:D / FT-NMR 1 (1), 680:C / RegBook 1 (1), 475:L / Structure Index 1 , 68:A:3

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
Signal word Warning {} {} {} {} {} {} {} {TCI}
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Ketones - Organic Building Blocks
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Terpenes

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