1-(Chloro-1-Pyrrolidinylmethylene)Pyrrolidinium Hexafluorophosphate 1-(氯-1-吡咯烷基亚甲基)吡咯烷六氟磷酸盐(PYClU)
CAS 135540-11-3 MFCD00191333
化学结构图
SMILES: F[P-](F)(F)(F)(F)F.ClC(N1CCCC1)=[N+]1CCCC1
化学属性
| Mol. Formula | C9H16ClF6N2P |
|---|---|
| Mol. Weight | 333 |
| Melting Point | 153-156 |
| TSCA | No |
| Density | 1.422 |
别名和识别编码
| Chemical Name | 1-(Chloro-1-Pyrrolidinylmethylene)Pyrrolidinium Hexafluorophosphate |
|---|---|
| Synonym | Chloro-N,N,N',N'-bis(tetramethylene)formamidinium Hexafluorophosphate |
| Beilstein Registry Number | 7898575 |
| PubChem Substance ID | 87566390 |
| CAS Number | 135540-11-3 |
| MDL Number | MFCD00191333 |
| Reaxys-RN | 4344959 |
| EC Number | 250-023-7 |
| Chemical Name Translation | 1-(氯-1-吡咯烷基亚甲基)吡咯烷六氟磷酸盐(PYClU) |
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信息真实价格透明
资金保障
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分类
- {SNA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
产品应用
- 新的结晶和非吸湿性多肽偶联试剂，特别是对N -甲基氨基酸
相关文献及参考
- 1. Yan-Zhang, et al Chem. Commun. 47 , 3897-3899, (2011)
- 2. Peng Li and Jie Cheng Xu Tetrahedron Lett. 40 , 8301-8304, (1999)
- 3. Ayman El-Faham, et al J. Heterocycl. Chem. 43 , 599-606, (2006)
- 4. Doris Kremzow, et al Chem. Eur. J. 11 , 1833-1853, (2005) 摘要
- 5. J. Coste et al. Tetrahedron Lett. 32 , 1967, (1991)
安全信息
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- 溶于乙腈
