Bromotris(Dimethylamino)Phosphonium Hexafluorophosphate 溴代三(二甲基氨基)磷六氟磷酸盐
CAS 50296-37-2 MFCD00191864
化学结构图
SMILES: CN(C)[P+](Br)(N(C)C)N(C)C.F[P-](F)(F)(F)(F)F
化学属性
| Mol. Formula | C6H18BrF6N3P2 |
|---|---|
| Mol. Weight | 388 |
| Melting Point | >300 |
| TSCA | No |
别名和识别编码
| Chemical Name | Bromotris(Dimethylamino)Phosphonium Hexafluorophosphate |
|---|---|
| Synonym | Bromotris(N-methylmethanaminato)-phosphorus hexafluorophosphate |
| MDL Number | MFCD00191864 |
| PubChem Substance ID | 160870946 |
| CAS Number | 50296-37-2 |
| Reaxys-RN | 14221932 |
| Chemical Name Translation | 溴代三(二甲基氨基)磷六氟磷酸盐 |
| Beilstein Registry Number | 14221932 |
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分类
- {SNA} Chemical Synthesis, Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
- {SA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
- {SNA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
相关文献及参考
- 1. J. M. Garcia, et al., Org. Lett. 11 , 3826-3829, (2009)
- 2. S. Bae and M. K. Lakshman, J. Org. Chem. 73 , 3707-3713, (2008)
- 3. C. Mordant, et al., Tetrahedron 63 , 6115-6123, (2007)
- 4. C. Salmi, et al., Lett. Org. Chem. 2 , 628-633, (2005)
- 5. C. M. Taylor, et al., J. Org. Chem. 70 , 1306-1315, (2005)
- 6. G. Depecker, et al., Org. Biomolecular Chem. 2 , 74-79, (2004)
- FT-IR 2 (1), 1553:C / Structure Index 1 , 169:A:8
安全信息
GHS Symbol
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H350 May cause cancer 可能致癌
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
- R34 Causes burns 会导致灼伤
- R45 May cause cancer 可能致癌
