2-Chloro-1,3-Dimethylimidazolidinium Hexafluorophosphate 2-氯-1,3-二甲基咪唑啉六氟磷酸盐(CIP)
CAS 101385-69-7 MFCD00191914
化学结构图
SMILES: CN1CC[N+](C)=C1Cl.F[P-](F)(F)(F)(F)F
化学属性
| Mol. Formula | C5H10ClF6N2P |
|---|---|
| Mol. Weight | 279 |
| Melting Point | 231-237 |
| Solubility | acetonitrile: 0.1 g/mL, clear |
别名和识别编码
| Chemical Name | 2-Chloro-1,3-Dimethylimidazolidinium Hexafluorophosphate |
|---|---|
| Synonym | 2-CHLORO-1,3-DIMETHYLIMIDAZOLINIUM PF6 2-Chloro-4,5-dihydro-1,3-dimethyl-1H-imidazolium hexafluorophosphate CIP 2-CHLORO-1,3-DIMETHYLIMIDAZOLINIUM HEXAFLUOROPHOSPHATE 98+% 2-Chloro-4,5-dihydro-1,3-dimethyl-1H-imidazolium hexafluorophosphate CIP 2-Chlor-1,3-dimethyl-imidazolidinium-hexafluorophosphat 2-CHLORO-1,3-DIMETHYLIMIDAZOLINIUM HEXAFLUOROPHOSPHATE 2-氯-1,3-二甲基咪唑六氟磷酸盐 2-CHLORO-1,3-DIMETHYL-2-IMIDAZOLINIUM HEXAFLUOROPHOSPHATE 2-CHLORO-1,3-DIMETHYLIMIDAZOLIDINIUM HEXAFLUOROPHOSPHATE |
| MDL Number | MFCD00191914 |
| PubChem Substance ID | 87566643 |
| Beilstein Registry Number | 5369058 |
| CAS Number | 101385-69-7 |
| Reaxys-RN | 5369058 |
| Chemical Name Translation | 2-氯-1,3-二甲基咪唑啉六氟磷酸盐(CIP) |
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分类
- {SA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
- {SNA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
相关文献及参考
- 1. M. Kitamura, et al., Synthesis 7 , 1037-1044, (2011)
- 2. J. H. M. Lange, et al., Bioorg. Med. Chem. Lett. 20 , 4992-4998, (2010)
- 3. M. I. Landsdell, et al., J. Med. Chem. 53 , 3183-3197, (2010)
- 4. J. H. M. Lange, et al., Bioorg. Med. Chem. Lett. 20 , 1084-1089, (2010)
- 5. N. Maulucci, et al., Chem. Commun. 33 , 3927-3929, (2008)
- 6. J. Ying, et al., J. Med. Chem. 49 , 6888-6896, (2006)
- FT-IR 2 (1), 577:C / Structure Index 1 , 56:D:2
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- TCI Shanghai:2-氯-1,3-二甲基咪唑啉六氟磷酸盐 2-Chloro-1,3-dimethylimidazolinium Hexafluorophosphate,>;98.0%(LC)(T)(101385-69-7)
