Bis(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Nickel(II) 双(2,2,6,6,-四甲基-3,5-庚二酮)镍(II)

CAS 14481-08-4 MFCD00192348

化学结构图

14481-08-4
SMILES: CC(C)(C)/C(=C\C(=O)C(C)(C)C)/O[Ni]O/C(=C/C(=O)C(C)(C)C)/C(C)(C)C

化学属性

Mol. FormulaNi(OCC(CH3)3CHCOC(CH3)3)2
Mol. Weight425.23
Melting Point219-223 °C(lit.)
TSCANo
Boiling Point90-110°/0.1mm subl.
Appearance purple xtl.
Stabilityhygroscopic

别名和识别编码

Chemical NameBis(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Nickel(II)
Synonym Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)nickel; Bis(2,2,6,6-tetramethylheptane-3,5-dionato)nickel(II) 双(2,2,6,6,-四甲基-3,5-庚二酮酸)镍(II) Ni(TMHD)2 Nickel(II)-DPM
MDL NumberMFCD00192348
PubChem Substance ID24865189
CAS Number14481-08-4
Chemical Name Translation双(2,2,6,6,-四甲基-3,5-庚二酮)镍(II)
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分类

  • {SNA} CVD and ALD Precursors by Metal, Micro/NanoElectronics, Nickel, Vapor Deposition Precursors, 材料科学
  • {SNA} CVD and ALD Precursors by Metal, Materials Science, Micro/NanoElectronics, Nickel, Vapor Deposition Precursors
  • {SA} CVD and ALD Precursors by Metal, Materials Science, Micro/NanoElectronics, Nickel, Vapor Deposition Precursors

相关文献及参考

  • Fieser 17 ,40
  • Structure Index 1 , 490:E:1

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P308+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H350 May cause cancer 可能致癌
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
Hazard Codes T
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S27/28
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Risk Statements
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R49 May cause cancer by inhalation 吸入会致癌
  • R45 May cause cancer 可能致癌
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类

  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Nickel Precursors 镍源
  1. CVD & ALD Precursors
  1. CVD & ALD Precursors
  2. Nickel
  1. Metal Beta-diketonates
  2. Nickel
  1. Metal TMHD / THD
  2. Nickel

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