2-(Triphenylphosphoranylidene)Acetonitrile (三苯基膦)乙腈
CAS 16640-68-9 MFCD00567633
化学结构图
SMILES: N#CC=P(c1ccccc1)(c1ccccc1)c1ccccc1
化学属性
| Mol. Formula | C20H16NP |
|---|---|
| Mol. Weight | 301 |
| Melting Point | 189-195 |
别名和识别编码
| Chemical Name | 2-(Triphenylphosphoranylidene)Acetonitrile |
|---|---|
| Synonym | (氰亚甲基)三苯基膦 Cyanomethyltriphenylphosphonium ylide |
| MDL Number | MFCD00567633 |
| PubChem Substance ID | 87577659 |
| CAS Number | 16640-68-9 |
| EC Number | 240-689-7 |
| Reaxys-RN | 750218 |
| Chemical Name Translation | (三苯基膦)乙腈 |
| Beilstein Registry Number | 750218 |
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分类
- {SA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- 1. H. Holla, et al., Bioorg. Med. Chem. Lett. 21 , 4793-4797, (2011)
- 2. C. Zhao, et al., J. Am. Chem. Soc. 133 , 10787-10789, (2011)
- 3. F. Ziyanak, et al., Adv. Synth. Catal. 353 , 897-902, (2011)
- 4. T. J. Martin, et al., Org. Lett. 13 , 2586-2589, (2011)
- 5. Y. Hiraga, et al., Tetrahedron Asymmetry 22 , 226-237, (2011)
- 6. F. Fang, et al., Eur. J. Org. Chem. 6 , 1084-1091, (2011)
- 7. M. Yuan, et al., J. Organomet. Chem. 696 , 905-912, (2011)
- 8. K. Lee, Bull. Korean Chem. Soc. 31 , 2776-2782, (2010)
- 9. J. Org. Chem. 72 , 4378, (2007) 摘要
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P305+P351+P338
- P301+P310+P330
- P302+P352+P312+P361+P364
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P405 Store locked up. 上锁保管。
- P305+P351+P338+P337+P313
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H301+H311+H331
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
