Bis(2,4-Dichlorophenyl) Phosphorochloridate 氯代磷酸双(2,4-二氯苯基)酯
CAS 14254-41-2 MFCD00674034
化学结构图
SMILES: O=P(Cl)(OC1=CC=C(Cl)C=C1Cl)OC1C=CC(Cl)=CC=1Cl
化学属性
| Mol. Formula | C12H6Cl5O3P |
|---|---|
| Mol. Weight | 406 |
| Melting Point | 51-56 ºC |
别名和识别编码
| Chemical Name | Bis(2,4-Dichlorophenyl) Phosphorochloridate |
|---|---|
| CAS Number | 14254-41-2 |
| Synonym | Phosphorochloridic Acid Bis(2,4-dichlorophenyl) Ester Bis(2,4-dichlorophenol) Phosphorochloridate Bis(2,4-dichlorophenyl) Phosphorochloridate 双(2,4-二氯苯基)磷酰氯 氯代磷酸双(2,4-二氯苯基)酯 |
| MDL Number | MFCD00674034 |
| PubChem Substance ID | 24869282 |
| Chemical Name Translation | 氯代磷酸双(2,4-二氯苯基)酯 |
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分类
- Aromatics
- Catalysts
- Pharmaceuticals
- Intermediates & Fine Chemicals
- Phosphorylating and Phosphitylating Agents,
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphorus Compounds, Phosphorus Halides
产品应用
- A phosphate catalyst used in the direct conversion of alcohols to azides via activation. It also acts as a coupling agent in the synthesis of oligonucleotide phosphorodithioates.
相关文献及参考
- Yu, C. et al.: Org. Lett., 2, 1959 (2000); Kamaike, K. et al.: Nucleic Acids. Res. Supp., 3, 93 (2003);
安全信息
GHS Symbol
- P301+P310
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H301 Toxic if swallowed 吞食有毒
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R22 Harmful if swallowed 吞咽有害
