3-Carboxy-5-Nitrophenylboronic Acid 3-羧基-5-硝基苯硼酸
CAS 101084-81-5 MFCD00757433
化学结构图
SMILES: [O-][N+](=O)C1C=C(C=C(C=1)B(O)O)C(O)=O
化学属性
| Mol. Formula | C7H6BNO6 |
|---|---|
| Mol. Weight | 211 |
| Melting Point | 248-252 |
| TSCA | No |
别名和识别编码
| Chemical Name | 3-Carboxy-5-Nitrophenylboronic Acid |
|---|---|
| CAS Number | 101084-81-5 |
| Alfabeta Name | CARBOXYNITROPHENYLBORONICACID 35--- |
| MDL Number | MFCD00757433 |
| Synonym | 3-Borono-5-nitrobenzoic acid;3-Carboxy-5-nitrophenylboronic acid |
| Reaxys-RN | 3329380 |
| Beilstein Registry Number | 16(4)1683 |
| PubChem Substance ID | 87561643 |
| Chemical Name Translation | 3-羧基-5-硝基苯硼酸 |
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分类
- Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
- {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
相关文献及参考
- Bektenova, G. A.; et al., Immobilization of glycoprotein enzymes on silica supports. II. Chemical immobilization of glucose oxidase and acetylcholinesterase on boronic acid-activated silica surfaces Izv. Akad. Nauk, Ser. Khim , 25-34, (2000)
- Coats, S. J.; et al., Parallel methods for the preparation and SAR exploration of N-ethyl-4-[(8-alkyl-8-aza-bicyclo[3.2.1]oct-3-ylidene)-aryl-methyl]-benzamides, powerful mu and delta opioid agonists Bioorg. Med. Chem. Lett. 14 , 5493-5498, (2004)
- Wu, H.; Hynes, J., Copper-Catalyzed Chlorination of Functionalized Arylboronic Acids Org. Lett. 12 , 1192-1195, (2010)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P305+P351+P338+P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
