2,4,6-Triisopropylbenzenesulfonyl azide 2,4,6-三异丙基苯磺酰叠氮化物
CAS 36982-84-0 MFCD00859286
化学结构图
SMILES: CC(C)C1C=C(C=C(C(C)C)C=1S(=O)(=O)N=[N+]=[N-])C(C)C
化学属性
| Mol. Formula | C15H23N3O2S |
|---|---|
| Mol. Weight | 309.43 |
| Melting Point | 39-44 °C |
| TSCA | No |
| Refractive index | n20/D 1.499 |
别名和识别编码
| Chemical Name | 2,4,6-Triisopropylbenzenesulfonyl azide |
|---|---|
| MDL Number | MFCD00859286 |
| Synonym | 2,4,6-Triisopropylbenzene-sulfonyl azide,contains 15 wt. % water as stabilizer {LY} 2,4,6-Triisopropylbenzene-sulfonyl azide,contains 15 wt. % water as stabilizer {} {LY} 2,4,6-Triisopropylbenzene-sulfonyl azide,contains 15 wt. % water as stabilizer {} {} {LY} 2,4,6-Triisopropylbenzene-sulfonyl azide,contains 15 wt. % water as stabilizer {} {} {} {LY} 2,4,6-Triisopropylbenzene-sulfonyl azide,contains 15 wt. % water as stabilizer {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-sulfonyl azide,contains 15 wt. % water as stabilizer {} {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-sulfonyl azide,contains 15 wt. % water as stabilizer {} {} {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-sulfonyl azide,contains 15 wt. % water as stabilizer {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-sulfonyl azide,contains 15 wt. % water as stabilizer {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-sulfonyl azide,contains 15 wt. % water as stabi |
| CAS Number | 36982-84-0 |
| Beilstein Registry Number | 2391566 |
| Chemical Name Translation | 2,4,6-三异丙基苯磺酰叠氮化物 |
| PubChem Substance ID | 354334425 |
| Reaxys-RN | 2391566 |
| Canonical SMILES | O=S(C1=C(C(C)C)C=C(C(C)C)C=C1C(C)C)(N=[N+]=[N-])=O |
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分类
- {SNA} Azidation/Diazo Transfer, Azides, Building Blocks, C-X Bond Formation (Non-Halogen), Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Synthetic Reagents, Various Azides
相关文献及参考
- Also used for azide transfer to potassium enolates (KHMDS) to form the ɑ-azido derivatives: J. Am. Chem. Soc., 109, 6881 (1987); 112, 4011 (1990); Tetrahedron Lett., 28, 6141 (1987). Other bases tend to favor diazo transfer. For further discussion and examples, see: Encyclopedia of Reagents for Organic Synthesis, L. A. Paquette, Ed., Wiley, Chichester (1995), vol. 7, p. 5174.
- Reagent for diazo transfer to ketones, e.g. under phase-transfer conditions, giving better yields of sterically-hindered ɑ-diazo ketones than other methods: Synthesis, 368 (1980); J. Am. Chem. Soc., 102, 6626 (1980); 113, 2598 (1991); Tetrahedron, 43, 5677 (1987).
安全信息
- S15 Keep away from heat 远离热源；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S37 Wear suitable gloves 戴适当手套；
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R5 Heating may cause an explosion 加热会引起爆炸
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P405 Store locked up. 上锁保管。
- P501a
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H301 Toxic if swallowed 吞食有毒
- H302 Harmful if swallowed 吞食有害
- H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
- H315 Causes skin irritation 会刺激皮肤
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
其他信息
- 2,4,6-三异丙基苯磺酰叠氮化物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L19383 2,4,6-三异丙基苯磺酰基叠氮化物, 98%, stab. with ca 10% water 2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water 5g 1806元 2010/05/25 L19383 2,4,6-三异丙基苯磺酰基叠氮化物, 98%, stab. with ca 10% water 2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water 1g 529元
- 上游原料:叠氮化钠 --> 2,4,6-三异丙基苯磺酰氯
- 检测方法:HPLC,NMR
- Alfa Aesar:2,4,6-三异丙基苯磺酰基叠氮化物,98%,stab.withca10%water 2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water(36982-84-0)
- MOL 文件:36982-84-0.mol
