(1R,2R)-N,N’-(Cyclohexane-1,2-Diyl)Bis(2-(DiphenylPhosphino)Benzamide) (1R,2R)-N,N-双(2-二苯基膦基苯甲酰)-1,2-环己二胺
CAS 138517-61-0 MFCD01631273
化学结构图
SMILES: O=C(N[C@@H]1CCCC[C@H]1NC(=O)C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1)C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | C44H40N2O2P2 |
|---|---|
| Mol. Weight | 690.75 |
| Melting Point | 136-142 °C |
| Stability | Pneumatic operation and storage |
| Appearance | white to off-white pwdr. |
别名和识别编码
| Chemical Name | (1R,2R)-N,N’-(Cyclohexane-1,2-Diyl)Bis(2-(DiphenylPhosphino)Benzamide) |
|---|---|
| Synonym | (R,R)-DACH-苯基 Trost 配体 N′-双(2-二苯基磷苯甲酰) (1R 2-二氨基环己烷-N (1R,2R)-(+)-1,2-二氨基环己烷-N,N′-双(2-二苯基磷苯甲酰) 2R)-(+)-1 |
| MDL Number | MFCD01631273 |
| CAS Number | 138517-61-0 |
| Chemical Name Translation | (1R,2R)-N,N-双(2-二苯基膦基苯甲酰)-1,2-环己二胺 |
| PubChem Substance ID | 329761529 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Trost Ligands
- {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Trost Ligands
相关文献及参考
- 1. Trost, B.M. et al. Chem. Rev. 96 , 395, (1996) 摘要
- 2. Trost, B.M. et al. Chem. Rev. 103 , 2921, (2003) 摘要
- 3. Trost, B.M. et al. J. Am. Chem. Soc. 124 , 11616, (2004)
- 4. Trost, B.M. et al. Aldrichimica Acta 40 , 59, (2007)
安全信息
其他信息
- 不对称烯丙基烷化反应的配体.
