2,5-Dichlorophenylboronic acid 2,5-二氯苯硼酸

CAS 135145-90-3 MFCD01863182

化学结构图

135145-90-3
SMILES: OB(O)C1C=C(Cl)C=CC=1Cl

化学属性

Mol. FormulaC6
Mol. Weight191
Melting Point150
TSCANo
Density1.47

别名和识别编码

Chemical Name2,5-Dichlorophenylboronic acid
CAS Number135145-90-3
Alfabeta NameDICHLOROPHENYLBORONICACID 25-,
MDL NumberMFCD01863182
Synonym 2,5-Dichlorobenzeneboronic acid 2,5-二氯苯硼酸 2,5-Dichlorophenylboronic acid
PubChem Substance ID87577944
Reaxys-RN4801290
Beilstein Registry Number4801290
EC Number250-023-7
Chemical Name Translation2,5-二氯苯硼酸
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分类

  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. Joshi, S. N.; et al., Regioselective iodination of chlorinated aromatic compounds using silver salts Tetrahedron 67 , 7461-7469, (2011)
  • 2. Ioannidou, H. A.; et al., Three-Step Synthesis of Ethyl Canthinone-3-carboxylates from Ethyl 4-Bromo-6-methoxy-1,5-naphthyridine-3-carboxylate via a Pd-Catalyzed Suzuki-Miyaura Coupling and a Cu-Catalyzed Amidation Reaction J. Org. Chem. 76 , 5113-5122, (2011)
  • 3. Morimoto, T.; et al., Rh(I)-Catalyzed CO Gas-Free Carbonylative Cyclization Reactions of Alkynes with 2-Bromophenylboronic Acids Using Formaldehyde Org. Lett. 11 , 1777-1780, (2009)
  • 4. Rao, H.; et al., Easy copper-catalyzed synthesis of primary aromatic amines by coupling aromatic boronic acids with aqueous ammonia at room temperature Angew. Chem. Int. Ed. Engl. 48 , 1114-1116, (2009)

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol

系列性分类