Disodium tetracarbonylferrate-dioxane (Collman's Reagent) 四羰基铁酸二钠盐-二噁烷
CAS 59733-73-2 MFCD02091641
化学结构图
SMILES: [Fe-2].[Fe-2].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[O+]#C[Na].[O+]#C[Na].[O+]#C[Na].[O+]#C[Na].C1COCCO1.C1COCCO1.C1COCCO1
化学属性
| Mol. Formula | Na2Fe(CO)4· 1.5C4H8O2 |
|---|---|
| Mol. Weight | 346.02 |
| TSCA | No |
别名和识别编码
| Chemical Name | Disodium tetracarbonylferrate-dioxane (Collman's Reagent) |
|---|---|
| Synonym | Sodium tetracarbonylferrate-dioxane 四羰基铁酸二钠合二噁烷 |
| MDL Number | MFCD02091641 |
| EC Number | 261-892-7 |
| CAS Number | 59733-73-2 |
| Chemical Name Translation | 四羰基铁酸二钠盐-二噁烷 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P222 Do not allow contact with air. 不要与空气接触。
- P422 Store contents under… 存储目录在…之下。
- P231+P232
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- H351 Suspected of causing cancer 怀疑致癌
- H331 Toxic if inhaled 吸入中毒
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
- H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
- R17 Spontaneously flammable in air 在空气中能够自燃
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R23 Toxic by inhalation 吸入有毒
