CAS 1330-78-5 MFCD02102116-Tritolyl phosphate 磷酸三甲酚酯 TAO{mole}

Tritolyl phosphate 磷酸三甲酚酯

CAS 1330-78-5 MFCD02102116

化学结构图

SMILES: Cc1ccc(OP(=O)(Oc2ccc(C)cc2)Oc2ccc(C)cc2)cc1.Cc1cccc(OP(=O)(Oc2cccc(C)c2)Oc2cccc(C)c2)c1.Cc1ccccc1OP(=O)(Oc1ccccc1C)Oc1ccccc1C

化学属性

Mol. Formula	C₂₁H₂₁O₄P
Mol. Weight	368.36
Refractive index	1.5550 to 1.5580
Boiling Point	-
Density	1.16
TSCA	Yes
Flash Point	-
Solubility	不溶
Autoignition Point	770 °F
Vapor Pressure	0.03 mmHg ( 25 °C)
Melting Point	<-40°C

别名和识别编码

Chemical Name	Tritolyl phosphate
Synonym	Celluflex 179C Disflamoll TKP Durad Imol S 140 Lindol PHOSPHORIC AC PHOSPHORIC ACID TRITOLYL EST Phosflex 179A Phosphorsäuretris(methylphenyl)ester Isomerengemisch Sumiguard TBT Tricresyl Phosphate (Mixture of Isomers: o-cresol, m-cresol, p-cresol) {} {} {} {} {} {} { {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} tricresyl phosphate {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} tricresilfosfati {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} phosphat {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} nci-c61041 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number	1330-78-5
PubChem Substance ID	87574512
EC Number	215-548-8
MDL Number	-
Merck Number	9763
Beilstein Registry Number	2384789
Chemical Name Translation	磷酸三甲酚酯
Wiswesser Line Notation	1R XOPO&OR X1&OR X1
LabNetwork Molecule ID	LN02135214
Canonical SMILES	-

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产品应用

用作环氧树脂胶粘剂的增塑剂，具有阻燃性能。

安全信息

GHS Symbol

WGK Germany2

Hazard statements

H303 May be harmfully swallowed 吞食可能有害
H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 6.1 T,N Xn,N,T

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312
P302+P352
P304+P340
P305+P351+P338
P308+P311
P308+P313
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

RTECSTD0175000

UN Number 2574 3082 UN 2574 6.1/PG 2 UN2574 UN2810

Safety Statements

S20/21 When using do not eat, drink or smoke 使用时，不得进食，饮水或吸烟；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
R50/53
R51/53
R62 Possible risk of impaired fertility 有削弱生殖能力的危险

Packing GroupII

Storage condition 4°C, Hygroscopic 贮存于阴凉、通风的库房内。

Hazard Class9

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 1800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARZNAD Arzneimittel-Forschung. Drug Research.  (Editio Cantor Verlag,
   Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.)  V.1-    1951-
   Volume(issue)/page/year: 7,585,1957

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - woman
DOSE/DURATION           : 70 mg/kg/14D
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Behavioral - changes in motor activity (specific assay)
   Behavioral - muscle weakness
REFERENCE :
   LANCAO Lancet.  (7 Adam St., London WC2N 6AD, UK)  V.1-    1823-
   Volume(issue)/page/year: 1,88,1981

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NPIRI* Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. (National
   Assoc. of Printing Ink Research Institute, Francis McDonald Sinclair
   Memorial Laboratory, Lehigh Univ., Bethlehem, PA 18015)
   Volume(i

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3900 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,114,1982

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 2250 mg/kg
SEX/DURATION            : male 7 day(s) pre-mating
                          female 7 day(s) pre-mating  - 22 day(s) after
                          conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - germ cell effects (in offspring)
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   10,344,1988

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 4550 mg/kg
SEX/DURATION            : male 13 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   TOXID9 Toxicologist.  (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway,
   Akron, OH 44311) V.1-    1981-  Volume(issue)/page/year: 6,292,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 7250 mg/kg
SEX/DURATION            : female 7 day(s) pre-mating
                          female 1-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - live birth index (measured after birth)
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   10,344,1988

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 1750 mg/kg
SEX/DUR

其他信息

灭火剂:水、泡沫、砂土、二氧化碳
毒性分级:中毒
刺激数据:皮肤- 兔子 500 毫克轻度; 眼- 兔子 500毫克/ 24小时轻度
上游原料:三氯氧磷 --> 氯 --> 二甲酚
职业标准:TLV-TWA 0.1 毫克/ 立方米
类别:有毒物品
无色或浅黄色油状液体，略带苯酚气味。工业品为三种异构体的混合物，通常尽可能除去毒性很大的邻位异构体，粘度(20 ℃)78～185mPa·s。溶于苯、醚类、醇类、油类。不溶于水，易燃、剧毒。
急性毒性:口服- 大鼠 LD50: 5190 毫克/ 公斤; 口服- 小鼠 LD50: 3900 毫克/ 公斤
图谱信息:磷酸三甲苯酯(1330-78-5)红外图谱(IR1) 磷酸三甲苯酯(1330-78-5)质谱(MS) 磷酸三甲苯酯(1330-78-5)红外图谱(IR2)
下游产品:邻磷酸三甲酚酯
用途一:用作分析试剂、硝化纤维的溶剂及增塑剂
Alfa Aesar:<1% Tritolyl phosphate, mixture of isomers, 98%, ortho-isomers <1%(1330-78-5)" href="http://www.alfa.com/zh/GP100w.pgm?DSSTK=A17433&CAS;=1330-78-5">磷酸三甲苯酯,异构体混合物,98%,ortho-isomers<1% Tritolyl phosphate, mixture of isomers, 98%, ortho-isomers <1%(1330-78-5)
蒸气压:0.03 mm Hg ( 25 °C)
TCI Shanghai:磷酸三甲苯酯(异构体的混合物) Tricresyl Phosphate (mixture of isomers),>;99.0%(GC)(1330-78-5)
Acros Organics:磷酸三甲苯酯，异构体混合物 Tritolyl phosphate, mixture of isomers, 99%(1330-78-5)
化学特性:磷酸三甲苯酯（1330-78-5）为异构体混合物，无色或微黄色透明油状液体。略带苯酚气味，稳定不挥发，具有良好的阻燃性、耐油性、电绝缘性、易加工性,不溶于水,与所有通用的有机溶剂混溶。工业品为三种异构体的混合物，通常尽可能除去毒性很大的邻位异构体。
磷酸三甲苯酯价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80134028 磷酸三甲酚酯 500ml 58元 2011/08/23 40059560 磷酸三甲酚酯 100g 14.2元 2011/04/16 P0273 磷酸三甲苯酯(异构体的混和物) Tricresyl Phosphate (mixture of isomers) 25G 124元
储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
外观性质:无色或淡黄色的透明油状液体。
用途三:用作环氧树脂胶粘剂的增塑剂，具有阻燃性能。
MOL 文件:1330-78-5.mol
Sigma Aldrich:1330-78-5(sigmaaldrich)
可燃性危险特性:遇明火、高热可燃; 燃烧时放出有毒的磷氧化物气体
用途二:磷酸三甲苯酯是生产乙烯基树脂、硝化纤维素、聚氯乙烯、电缆橡胶制品及软质聚氨酯泡沫塑料等的重要的增塑.阻燃型添加剂, 与高聚物有良好的耐磨性、耐侯性、防霉性耐辐射性及电性能:还是一种调治机齿轮油、润滑油的重要极压抗磨剂。
MSDS 信息:磷酸三甲苯酯(1330-78-5).msds