Fluoro-N,N,N,N-Tetramethylformamidinium Hexafluorophosphate 四甲基氟代脲六氟磷酸酯
CAS 164298-23-1 MFCD02684443
化学结构图
SMILES: CN(C)C(F)=[N+](C)C.F[P-](F)(F)(F)(F)F
化学属性
| Mol. Formula | C5H12F7N2P |
|---|---|
| Mol. Weight | 264 |
| Melting Point | 104-109 |
| TSCA | No |
别名和识别编码
| Chemical Name | Fluoro-N,N,N,N-Tetramethylformamidinium Hexafluorophosphate |
|---|---|
| Synonym | 四甲基氟代脲六氟磷酸酯,TFFH TFFH N,N,N',N'-Tetramethylfluoroformamidiniun hexafluorophosphate Fluoro-N,N,N',N'-tetramethylformamidinium hexafluorophosphate |
| MDL Number | MFCD02684443 |
| PubChem Substance ID | 87561692 |
| CAS Number | 164298-23-1 |
| Reaxys-RN | 7321765 |
| Beilstein Registry Number | 7321765 |
| Chemical Name Translation | 四甲基氟代脲六氟磷酸酯 |
| InChIKey | ZAVXOOLKAGPJPI-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00170430 |
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分类
- {SA} Chemical Biology, Chemical Synthesis, Coupling, Fluorination, Fluorination Reagents, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
- {SNA} Chemical Biology, Chemical Synthesis, Coupling, Fluorination,
产品应用
- 用于多肽缩合剂。
相关文献及参考
- 1. T. Hansen, et al., J. Med. Chem. 54 , 858-868, (2011)
- 2. S. Froelund, et al., J. Med. Chem. 53 , 7441-7451, (2010)
- 3. T. Hansen, et al., J. Med. Chem. 53 , 595-606, (2010)
- 4. R. B. Silverman, et al., Bioorg. Med. Chem. 17 , 7593-7605, (2009)
- 5. M. Jin, et al., Bioorg. Med. Chem. Lett. 21 , 1176-1180, (2011)
- 6. F. M. Brunel, et al., Nano Lett. 10 , 1093-1097, (2010)
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P305+P351+P338+P337+P313
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S37 Wear suitable gloves 戴适当手套；
