2-Chloro-3-Pyridylboronic Acid 2-氯吡啶-3-硼酸
CAS 381248-04-0 MFCD03094997
化学结构图
SMILES: OB(O)C1C=CC=NC=1Cl
化学属性
| Mol. Formula | C5 |
|---|---|
| Mol. Weight | 157 |
| Melting Point | 151-153 |
| TSCA | No |
| Density | 1.41 |
别名和识别编码
| Chemical Name | 2-Chloro-3-Pyridylboronic Acid |
|---|---|
| CAS Number | 381248-04-0 |
| Alfabeta Name | CHLOROPYRIDINEBORONICACID 23--- |
| MDL Number | MFCD03094997 |
| Synonym | 2-氯吡啶-3-硼酸 (2-Chloropyridin-3-yl)boronic acid (2-Chloro-3-pyridyl)boronic acid Dihydroxy(2-chloro-3-pyridyl)borane (2-Chloro-3-pyridyl)boronic acid (2-Chloropyridin-3-yl)boronic acid Dihydroxy(2-chloro-3-pyridyl)borane |
| Reaxys-RN | 9119913 |
| EC Number | 000-000-0 |
| Beilstein Registry Number | 9119913 |
| Chemical Name Translation | 2-氯吡啶-3-硼酸 |
| PubChem Substance ID | 135727096 |
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分类
- {SNA} Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Heteroaryl Boronic Acids, Organometallic Reagents
相关文献及参考
- 1. Ioannidou, H. A.; et al., Three-Step Synthesis of Ethyl Canthinone-3-carboxylates from Ethyl 4-Bromo-6-methoxy-1,5-naphthyridine-3-carboxylate via a Pd-Catalyzed Suzuki-Miyaura Coupling and a Cu-Catalyzed Amidation Reaction J. Org. Chem. 76 , 5113-5122, (2011)
- 2. Grob, J. E.; et al., One-pot reductive amination and Suzuki-Miyaura cross-coupling of formyl aryl and heteroaryl MIDA boronates in array format J. Org. Chem. 76 , 4930-4940, (2011)
- 3. Crombie, A. L.; et al., Synthesis and evaluation of azabicyclo[3.2.1]octane derivatives as potent mixed vasopressin antagonists Bioorg. Med. Chem. Lett. 20 , 3742-3745, (2010)
- 4. Voisin-Chiret, A. S.; et al., A general synthesis of halo-oligopyridines. The Garlanding concept Tetrahedron 65 , 607-612, (2009)
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P332+P313
- P304+P340
- P301+P312
- P302+P352
- P305+P351+P338+P337+P313
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
