5-Fluoro-2-Methylphenylboronic Acid 5-氟-2-甲基苯硼酸

CAS 163517-62-2 MFCD03095047

化学结构图

163517-62-2
SMILES: CC1C=CC(F)=CC=1B(O)O

化学属性

Mol. FormulaC7H8BFO2
Mol. Weight153.95
Melting Point144-148°C
TSCANo
Density1.2
Boiling Point287.7±50.0°C at 760 mmHg

别名和识别编码

Chemical Name5-Fluoro-2-Methylphenylboronic Acid
CAS Number163517-62-2
Alfabeta NameFLUOROMETHYLPHENYLBORONICACID 52---
MDL NumberMFCD03095047
Synonym 5-Fluoro-2-methylphenylboronic acid {LY} 5-Fluoro-2-methylphenylboronic acid {} {LY} 5-Fluoro-2-methylphenylboronic acid {} {} {LY} 5-Fluoro-2-methylphenylboronic acid {} {} {} {LY} 5-Fluoro-2-methylphenylboronic acid {} {} {} {} {LY} 5-Fluoro-2-methylphenylboronic acid {} {} {} {} {} {LY} 5-Fluoro-2-methylphenylboronic acid {} {} {} {} {} {} {LY} 5-Fluoro-2-methylphenylboronic acid {} {} {} {} {} {} {} {LY} 5-Fluoro-2-methylphenylboronic acid {} {} {} {} {} {} {} {} {LY} 5-Fluoro-2-methylphenylboronic acid {} {} {} {} {} {} {} {} {} {LY} 5-Fluoro-2-methylphenylboronic acid {} {} {} {} {} {} {} {} {} {} {LY} 5-Fluoro-2-methylphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Fluoro-2-methylphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Fluoro-2-methylphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Fluoro-2-methylphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Fluoro
PubChem Substance ID253662227
EC Number000-000-0
Beilstein Registry Number2384789
Chemical Name Translation5-氟-2-甲基苯硼酸
Reaxys-RN9697059
Canonical SMILESCC1=CC=C(F)C=C1B(O)O
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分类

  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. Dong, C.-G.; et al., Monoarylation of dibromoarenes by simple palladium catalyst systems: efficient synthesis of bromobiaryls from dibromoarenes and arylboronic acids Synlett , 1081-1086, (2009)
  • 2. Partyka, D. V.; Gray, T. G. , Facile syntheses of homoleptic diarylmercurials via arylboronic acids J. Organomet. Chem. 694 , 213-218, (2009)
  • 3. Kim, H. H.; et al., Highly efficient synthesis of 2-aryl-3-methoxyacrylates via Suzuki-Miyaura coupling reaction Bull. Korean Chem. Soc. 27 , 191-192, (2006)
  • 4. Lee, S.; et al., (5-Arylfuran-2-ylcarbonyl)guanidines as Cardioprotectives through the Inhibition of Na+/H+ Exchanger Isoform-1 J. Med. Chem. 48 , 2882-2891, (2005)

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Signal word
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
Packing Groupn/a
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  6. Disubstituted Aryl Boronic Acids - Aryl Boronic Acids
  1. Functional Group 官能团索引
  2. boronic acid

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