1-(Bromomethyl)-3,5-di-Tert-Butylbenzene 3,5-二叔丁基苄溴
CAS 62938-08-3 MFCD03701623
化学结构图
SMILES: CC(C)(C)C1C=C(CBr)C=C(C=1)C(C)(C)C
化学属性
| Mol. Formula | C15H23Br |
|---|---|
| Mol. Weight | 283.25 |
别名和识别编码
| Chemical Name | 1-(Bromomethyl)-3,5-di-Tert-Butylbenzene |
|---|---|
| Synonym | 1-(Bromomethyl)-3,5-bis(1,1-dimethylethyl)benzene 1-(Bromomethyl)-3,5-bis(1,1-dimethylethyl)benzene 1-溴甲基-3,5-二叔丁基苯 a-Bromo-3,5-di-tert-butyltoluene 1-溴甲基-3,5-二叔丁基苯 a-Bromo-3,5-di-tert-butyltoluene 3,5-二叔丁基苄溴 |
| MDL Number | MFCD03701623 |
| PubChem Substance ID | 87569073 |
| CAS Number | 62938-08-3 |
| Reaxys-RN | 1951239 |
| Chemical Name Translation | 3,5-二叔丁基苄溴 |
| LabNetwork Molecule ID | LN00188223 |
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分类
- {SNA} Aryl, Building Blocks, C13 to C37+, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
- Aryl, Building Blocks, C13 to C37+, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
相关文献及参考
- 1. H. Kawai, et al., , Cu-Mediated Chemoselective Trifluoromethylation of Benzyl Bromides Using Shelf-Stable Electrophilic Trifluoromethylating Reagents Org. Lett. 13 , 3596-3599, (2011)
- 2. J. E. B. McCallum, et al., , Synthesis of lipophilic N 9-benzylguanine derivatives Synlett 19 , 2871-2874, (2010)
- 3. K. A. Davies, et al., , Operationally Simple Copper-Promoted Coupling of Terminal Alkynes with Benzyl Halides J. Org. Chem. 74 , 3997-4000, (2009)
- 4. S. Park, et al., , Near-infrared solid-state fluorescent naphthooxazine dyes attached with bulky dibutylamino and perfluoroalkenyloxy groups at 6- and 9-positions Tetrahedron Lett. 50 , 1131-1135, (2009)
- 5. D. Fournier and D. Poirier, et al., , Chemical synthesis and evaluation of 17 a -alkylated derivatives of estradiol as inhibitors of steroid sulfatase Eur. J. Med. Chem. 46 , 4227-4237, (2011)
- 6. T. Hansen, et al., , Antimicrobial Activity of Small ß-Peptidomimetics Based on the Pharmacophore Model of Short Cationic Antimicrobial Peptides J. Med. Chem. 53 , 595-606, (2010)
安全信息
GHS Symbol
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P330+P331+P310
- P303+P361+P353
- P304+P340
- P305+P351+P338
- P304+P340+P310
- H290 May be corrosive to metals 可能腐蚀金属。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
