3-Aminopyridine 3-氨基吡啶

CAS 462-08-8 MFCD00006400

化学结构图

462-08-8
SMILES: Nc1cccnc1

化学属性

Mol. FormulaC5H6N2
Mol. Weight94
Boiling Point248
Melting Point60-63
TSCAT
Density1.107
Flash Point88°(190°F)
Stability易吸潮
Solubility溶于水、乙醇、乙醚、苯。

别名和识别编码

Chemical Name3-Aminopyridine
CAS Number462-08-8
Alfabeta NameAMINOPYRIDINE 3-
MDL NumberMFCD00006400
EC Number207-322-2
Beilstein Registry Number105692
Synonym 3-Pyridinamine 3-Pyridylamine 3-吡啶胺 3-氨基吡啶 AMINOPYRIDINE, 3- Amino-3 pyridine TIMTEC-BB SBB004395
Merck Number473
PubChem Substance ID87562047
Reaxys-RN105692
Chemical Name Translation3-氨基吡啶
Wiswesser Line NotationT6NJ CZ
LabNetwork Molecule IDLN00002491
InChIInChI=1S/C5H6N2/c6-5-2-1-3-7-4-5/h1-4H,6H2
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分类

  • {SNA} Building Blocks, C5, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

产品应用

  • 可作药物和染料的中间体;分析试剂。

相关文献及参考

  • Merck: 14,473
  • Merck: 14,473 Beilstein:22(3/4)4067

安全信息

Warnings 危化品目录(2015) AIR SENSITIVE, HYGROSCOPIC, TOXIC
Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R25 Toxic if swallowed 吞咽有毒
  • R33 Danger of cumulative effects 有累积作用的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P310+P330
  • P302+P350
  • P302+P352+P310+P361+P364
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P332+P313
  • P337+P313
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSUS1650000
Packing GroupII
UN Number 2671
Storage condition Air Sensitive & Hygroscopic Poison room 易吸湿,密封保存。
Hazard statements
  • H300+H310+H330
  • H315 Causes skin irritation 会刺激皮肤
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes 6.1 T T,Xi
Hazard Class6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 178 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 13300 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 30 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AEPPAE Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und
   Pharmakologie.  (Berlin, Ger.) V.110-253, 1925-66.  For publisher
   information, see NSAPCC.  Volume(issue)/page/year: 226,163,1955

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : In

{hazard_

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intracerebral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   AJEBAK Australian Journal of Experimental Biology and Medical Science.
   (Adelaide, S.A., Australia) V.1-64, 1924-86.  Volume(issue)/page/year:
   36,365,1958

Restrict 危险品

其他信息

  • F:3-8-9-23
  • 3-氨基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0413 3-氨基吡啶 3-Aminopyridine 25G 176元 2014/06/02 A0413 3-氨基吡啶 3-Aminopyridine 500G 1450元 2010/06/21 104561000 3-氨基吡啶 3-Aminopyridine 99% 100 GR 640元
  • Hazard Note:Toxic/Irritant
  • Acros Organics:3-氨基吡啶 3-Aminopyridine, 99%(462-08-8)
  • 下游产品:3-碘-2-硝基吡啶 --> 3-氨基-2-甲氧基-6-溴吡啶 --> N-(4-甲酰基吡啶-3-基)-2,2-二甲基丙酰胺 --> (4-甲酰基吡啶-3-基)氨基甲酸叔丁酯 --> 哌仑西平 --> 2,6-二氯-3-氨基吡啶 --> 3-碘吡啶 --> 2,6-二溴-3-氨基吡啶
  • 灭火剂:干粉、二氧化碳、砂土、泡沫
  • MSDS 信息:间氨基吡啶(462-08-8).msds
  • 上游原料:氢氧化钾 --> 叔丁醇 --> 酸性氧化铝 --> 烟酰胺 --> 四乙酸铅
  • 检测方法:GC,NMR
  • 用途一:可作药物和染料的中间体;分析试剂。
  • Sigma Aldrich:462-08-8(sigmaaldrich)
  • 类别:有毒物品
  • 溶于水、乙醇、苯和乙醚,不溶于石油醚。有吸潮性。
  • 图谱信息:3-氨基吡啶(462-08-8)核磁图( 13 CNMR) 3-氨基吡啶(462-08-8)质谱(MS) 3-氨基吡啶(462-08-8)红外图谱(IR2) 3-氨基吡啶(462-08-8)红外图谱(IR1) 3-氨基吡啶(462-08-8)核磁图( 1 HNMR)
  • MOL 文件:462-08-8.mol
  • Alfa Aesar:3-氨基吡啶,99% 3-Aminopyridine, 99%(462-08-8)
  • 急性毒性:腹腔-小鼠 LD50: 28 毫克/公斤; 皮下-小鼠LD50: 30 毫克/公斤
  • 方法一:由烟酰胺制得。
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 毒性分级:剧毒
  • TSCA:T
  • 可燃性危险特性:明火可燃; 受热分解有毒氧化氮气体
  • 敏感性:Air Sensitive & Hygroscopic
  • TCI Shanghai:3-氨基吡啶 3-Aminopyridine,>;99.0%(GC)(T)(462-08-8)
  • 海关编码:29333999
  • 外观性质:白色至淡黄色针状结晶。

系列性分类