(R)-Glycidylphenylether (R)-苯基缩水甘油醚
CAS 71031-02-2 MFCD06659025
化学结构图
SMILES: C(OC1C=CC=CC=1)C1CO1
化学属性
| Mol. Formula | C9H10O2 |
|---|---|
| Mol. Weight | 150.18 |
| Refractive index | 1.5290 to 1.5330 |
别名和识别编码
| Chemical Name | (R)-Glycidylphenylether |
|---|---|
| Synonym | (R)-2-苯氧甲基环氧乙烷 (R)-α-(2-环氧乙基)苯甲醚 (R)-缩水甘油基苯基醚 (R)-Phenoxymethyloxirane (R)-α-(2-环氧乙基)苯甲醚 (R)-缩水甘油基苯基醚 (R)-Phenoxymethyloxirane |
| MDL Number | MFCD06659025 |
| PubChem Substance ID | 354335814 |
| CAS Number | 71031-02-2 |
| Chemical Name Translation | (R)-苯基缩水甘油醚 |
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信息真实价格透明
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks
相关文献及参考
- 1. K. S. MacMillan, et al., , Development of Proneurogenic, Neuroprotective Small Molecules J. Am. Chem. Soc. 133 , 1428-1437, (2011)
- 2. D. Sun, et al., , Discovery, synthesis, and biological evaluation of piperidinol analogs with anti-tuberculosis activity Bioorg. Med. Chem. 17 , 3588-3594, (2009)
- 3. D. Albanese, et al., , Synthesis of 2-substituted 3,4-dihydro-2 H -1,4-benzoxazines through ligandless copper-catalyzed cyclization of hydroxy sulfonamides under phase-transfer catalysis conditions J. Mol. Catal. A: Chem. 288 , 28-32, (2008)
- 4. M. Sivaprakasam, et al., , A straightforward synthesis of enantiopure bicyclic azetidines Eur. J. Org. Chem. 34 , 5734-5739, (2007)
- 5. K. Rueck-Braun and T. Freysoldt, , Synthesis by addition across C-O bonds Sci. Synth. 35 , 503-521, (2006)
- 6. S. Wu, et al., , A novel enantioselective epoxide hydrolase for ( R )-phenyl glycidyl ether to generate ( R )-3-phenoxy-1,2-propanediol Appl. Microbiol. Biotechnol. 76 , 1281-1287, (2007)
安全信息
GHS Symbol
- P305+P351+P338
- P308+P313
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P304+P340+P312
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P405 Store locked up. 上锁保管。
- P273 Avoid release to the environment. 避免释放到环境中。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P305+P351+P338+P337+P313
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- P403+P233
- P302+P352+P312+P362+P364
- H332 Harmful if inhaled 吸入有害
- H315 Causes skin irritation 会刺激皮肤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H312 Harmful in contact with skin 皮肤接触有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H350 May cause cancer 可能致癌
- H318 Causes serious eye damage 严重伤害眼睛
- H312+H332
- H303 May be harmfully swallowed 吞食可能有害
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
- R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
- R45 May cause cancer 可能致癌
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R52/53
- R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
- R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
