(S)-3,3′-Bis(Triphenylsilyl)-1,1′-Binaphthyl2,2′-Diyl Hydrogenphosphate (S)-3,3′-双(三苯甲硅烷基)-1,1′-联萘-2,2′-二酚磷酸酯
CAS 929097-92-7 MFCD09265079
化学结构图
SMILES: OP1(=O)OC2=C(C3=C(O1)C(=CC1C=CC=CC=13)[Si](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1C=C2[Si](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | C56H41O4PSi2 |
|---|---|
| Appearance | white to light-yellow solid |
| Mol. Weight | 865 |
| Melting Point | 329-335°C |
别名和识别编码
| Chemical Name | (S)-3,3′-Bis(Triphenylsilyl)-1,1′-Binaphthyl2,2′-Diyl Hydrogenphosphate |
|---|---|
| Synonym | (11bR)-4-羟基-2,6-双(三苯甲硅烷基)二萘并-[2,1-d:1′,2′f]-1,3,2-二恶磷环庚烷-4-氧化物 Carreira SALDIPAC Ligand MacMillan TiPSY 催化剂 (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d1,2f]-[1,3,2]-dioxaphosphepin 4-oxide (11bS)-4-羟基-2,6-双(三苯甲硅烷基)二萘并-[2,1-d1′,2′f]-[1,3,2]-二恶磷环庚烷-4-氧化物 MacMillan TiPSY 催化剂 |
| MDL Number | MFCD09265079 |
| PubChem Substance ID | 24885544 |
| Chemical Name Translation | (S)-3,3′-双(三苯甲硅烷基)-1,1′-联萘-2,2′-二酚磷酸酯 |
| CAS Number | 929097-92-7 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Phosphoric Acids
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
