(S)-Ru(OAc)2(H8-BINAP) 二乙酸根[(S)-(-)-2,2'-二(二苯基膦基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘基]钌(II)
CAS 142962-95-6 MFCD09753023
化学结构图
SMILES:
化学属性
| Mol. Formula | C48H46O4P2Ru |
|---|---|
| Mol. Weight | 849.89 |
| Appearance | yellow to dark brown solid |
| Stability | air sensitive |
| Melting Point | >100°C dec. |
别名和识别编码
| Chemical Name | (S)-Ru(OAc)2(H8-BINAP) |
|---|---|
| Synonym | (S)-Ru(OAc)2(H8-BINAP) 二乙酸根[(S)-(-)-2,2′-二(二苯基膦基)-5,5′,6,6′,7,7′,8,8′-八氢-1,1′-联萘基]钌(II) |
| PubChem Substance ID | 329761578 |
| Chemical Name Translation | 二乙酸根[(S)-(-)-2,2'-二(二苯基膦基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘基]钌(II) |
| MDL Number | MFCD09753023 |
| CAS Number | 142962-95-6 |
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分类
- {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
- Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
相关文献及参考
- Shinohara, T.; et al., Practical stereoselective synthesis of (2,3,4,5-tetrahydro-1H-benz[b]azepin-5-yl)acetic acid Chirality 12 , 425-430, (2000)
- Uemura, T.; et al., Highly Efficient Enantioselective Synthesis of Optically Active Carboxylic Acids by Ru(OCOCH3)2[(S)-H8-BINAP] J. Org. Chem. 61 , 5510-5516, (1996)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
