1,2:4,5-Di-O-Isopropylidene-Beta-D-Erythro-2,3-Hexodiulo-2,6-Pyranose 1,2:4,5-二-O-异亚丙基-Beta-D-赤式-2,3-二酮-2,6-吡喃糖
CAS 18422-53-2 MFCD00063383
化学结构图
SMILES: CC1(C)OC2COC3(COC(C)(C)O3)C(=O)C2O1
化学属性
| Mol. Formula | C12H18O6 |
|---|---|
| Mol. Weight | 258 |
| Melting Point | 102-104 |
| TSCA | No |
别名和识别编码
| Chemical Name | 1,2:4,5-Di-O-Isopropylidene-Beta-D-Erythro-2,3-Hexodiulo-2,6-Pyranose |
|---|---|
| MDL Number | MFCD00063383 |
| Synonym | 1,2:4,5-Di-O-isopropylidene-beta-D-erythro-2,3-hexodiulo-2,6-pyranose |
| EC Number | 000-000-0 |
| CAS Number | 18422-53-2 |
| Beilstein Registry Number | 1319073 |
| Chemical Name Translation | 1,2:4,5-二-O-异亚丙基-Beta-D-赤式-2,3-二酮-2,6-吡喃糖 |
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相关文献及参考
- Developed by Shi's group for the enantioselective epoxidation of alkenes. Used in substoichiometric amounts in the presence of OxoneTM or hydrogen peroxide, a chiral dioxirane is formed which converts trans-disubstituted and trisubstituted alkenes to epoxides with high ee: J. Am. Chem. Soc., 119, 11224 (1997); Tetrahedron Lett., 40, 8721 (1999). Selective monoepoxidation of dienes: J. Org. Chem., 63, 2948 (1998), or enynes: Tetrahedron Lett., 39, 4425 (1998), can be achieved. Has also been applied to the kinetic resolution of racemic cyclic olefins: J. Am. Chem. Soc., 121, 7718 (1999).
安全信息
GHS Symbol
