Octacarbonyldicobalt 八羰基二钴
CAS 10210-68-1 MFCD00016024
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- Catalyst
- {uni_hamburg} no charge; metal-organic; other heterocycle; fused rings; 3ring; 4ring; metal carbonyl; 1fragment
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Cobalt, Non-Precious Metal Catalysis
- Miscellaneous Reagents
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Cobalt
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Cobalt, Cobalt Catalysts, Non-Precious Metal Catalysis
产品应用
- Cobalt Carbonyl is a metal carbonyl used as a reagent and catalyst in organometallic chemistry and organic synthesis. Cobalt Carbonyl is commonly used as a hydroformylation catalyst for the conversion
相关文献及参考
- {
- Short: III/20b
- Short: III/35D5
- Mirbach, M. et al.: J. Am. Chem. Soc., 103, 7594 (1981); Haukka, M. et al.: J. Mol. Cat. A Chem., 102, 79 (1995); Haumann, M. et al.: Catal. Tod., 79, 43 (2003);
- The reaction has been exploited as a powderful tool in the synthesis of complex molecules. For reviews, see: Org. React., 40, 1 (1991); Chem. Soc. Rev., 33, 32 (2004).
- Reagent used in the Pauson-Khand reaction, a formal [2 + 2 + 1] cycloaddition of an alkyne, and alkene and carbon monoxide to form a cyclopentenone: J. Chem. Soc., Perkin 1, 977 (1973):
安全信息
GHS Symbol
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P302+P352+P333+P313+P362+P364
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P304+P340+P310
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P301+P312+P330
- P302+P350
- P337+P313
- P308+P313
- P403+P233
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P273 Avoid release to the environment. 避免释放到环境中。
- P305+P351+P338+P337+P313
- P405 Store locked up. 上锁保管。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- H302 Harmful if swallowed 吞食有害
- H315 Causes skin irritation 会刺激皮肤
- H330 Fatal if inhaled 吸入致命
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H351 Suspected of causing cancer 怀疑致癌
- H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
- H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
- H251 Self-heating: may catch fire 自我放热:可能着火
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- R11 Highly flammable 非常易燃
- R52/53
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R22 Harmful if swallowed 吞咽有害
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R26 Very toxic by inhalation 吸入极毒
- R48/20
- R62 Possible risk of impaired fertility 有削弱生殖能力的危险
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 378 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 38(1),97,1973
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 26900 ug/m3/2H TOXIC EFFECTS : Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - dyspnea REFERENCE : VRDEA5 Vrachebnoe Delo. Medical Practice. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) No.1- 1918- Volume(issue)/page/year: (2),101,1969
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 165 mg/m3 TOXIC EFFECTS : Lungs, Thorax, or Respiration - acute pulmonary edema REFERENCE : VRDEA5 Vrachebnoe Delo. Medical Practice. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) No.1- 1918- Volume(issue)/page/year: (2),101,1969
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 754 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 38(1),97,1973