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分类

• {SNA} Aliphatic halogenated, Analytical Standards, Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks, 农残和代谢标准品, 分析/色谱, 灭草剂
• {SNA} Aliphatic halogenated,
• {SNA} Aliphatic halogenated, Analytical Standards, Analytical/Chromatography, Building Blocks, C3 to C6, Carbonyl Compounds,
• {uni_hamburg} no charge; ketone; 1fragment
• {SNA} Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
• {SNA} Aliphatic halogenated, Analytical Standards, Analytica

相关文献及参考

• Reagent for protection of amino groups as their N-trichloroacetyl derivatives under neutral conditions: J. Org. Chem., 35, 2423 (1970); Org. Synth. Coll., 5, 1074 (1973). The group can be cleaved with NaBH4 in ethanol: Chem. Ber., 103, 2437 (1970).
• In combination with triphenylphosphine, converts primary and secondary allylic alcohols to their chlorides without isomerization: Tetrahedron Lett., 2999 (1977). Tertiary allylic alcohols do undergo allylic rearrangement to give the less substituted chloride: J. Org. Chem., 44, 359 (1979), but cyclopropyl carbinols are converted to their chlorides without rearrangement: J. Org. Chem., 49, 431 (1984). The method is also applicable to the mild conversion of carboxylic acids to acid chlorides: Tetrahedron Lett., 38, 6489 (1997); see also Trichloroacetonitrile, A10565.
• With strong base, e.g. alkoxide, is a source of dichlorocarbene. For a review, see: Org. React., 13, 55 (1963).
• Short: II/2
• Beilstein:1,657

安全信息

GHS Symbol

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 920 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,72,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 240 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,72,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2980 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel,"
   Perkow, W., Berlin, Verlag Paul Parey, 1971-1976  Volume(issue)/page/year:
   -,-,1971/1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCOC** Pesticide Chemicals Official Compendium, Association of the American
   Pesticide Control Officials, Inc., 1966.  (Topeka, KS)
   Volume(issue)/page/year: -,580,1966

TYPE OF TEST

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 10 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 155,53,1985

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 700 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 89,137,1981

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ng/plate
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 24,590,1980

其他信息

• 海关编码:29147090
• 储运特性:库房通风低温干燥; 与食品原料分开储运
• 类别:农药
• 六氯丙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0335 六氯丙酮 Hexachloroacetone 500G 835元 2014/06/02 H0335 六氯丙酮 Hexachloroacetone 25G 104元 2010/05/25 B23259 六氯丙酮, 99% Hexachloroacetone, 99% 1kg 949元
• 毒性分级:剧毒
• Sigma Aldrich:116-16-5(sigmaaldrich)
• 图谱信息:六氯丙酮(116-16-5)Raman光谱 六氯丙酮(116-16-5)质谱(MS) 六氯丙酮(116-16-5)核磁图( 13 CNMR) 六氯丙酮(116-16-5)红外图谱(IR2) 六氯丙酮(116-16-5)红外图谱(IR1)
• MSDS 信息:六氯丙酮(116-16-5).msds
• 六氯丙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 H0335 六氯丙酮 Hexachloroacetone 500G 981元 2011/04/16 H0335 六氯丙酮 Hexachloroacetone 25G 109元 2010/05/25 B23259 六氯丙酮, 99% Hexachloroacetone, 99% 1kg 949元
• Alfa Aesar:六氯丙酮,99% Hexachloroacetone, 99%(116-16-5)
• 外观性质:无色液体。
• 职业标准:STEL 0.5 毫克/ 立方米
• F:19
• 灭火剂:干粉、泡沫、砂土
• 可燃性危险特性:燃烧产生有毒氯化物气体
• 微溶于水，溶于丙酮。
• MOL 文件:116-16-5.mol
• 急性毒性:口服- 大鼠 LD50: 240 毫克/ 公斤
• TCI Shanghai:六氯丙酮 Hexachloroacetone,>;98.0%(GC)(116-16-5)
• 用途一:用于生产医药、农药中间体