CAS 90-04-0 MFCD00007688-o-Anisidine 邻甲氧基苯胺 TAO{mole}

o-Anisidine 邻甲氧基苯胺

CAS 90-04-0 MFCD00007688

化学结构图

SMILES: COC1CCCCC1N

化学属性

Mol. Formula	C7H9NO
Mol. Weight	123
Refractive index	1.5730 to 1.5770
Boiling Point	225
Density	1.092
Melting Point	3-6
Flash Point	111°C(lit.)
TSCA	Yes
Solubility	Solubility in water: 13 g/L (20°C) Solubility in other solvents: Soluble in dilute mineral acid Miscible with alcohol and ether Soluble in acetone and benzene
Stability	对光敏感

别名和识别编码

Chemical Name	o-Anisidine
CAS Number	90-04-0
Alfabeta Name	ANISIDINE O-
MDL Number	MFCD00007688
Synonym	2-METHOXYANILINE 邻茴香胺 o-Aminoanisole o-Methoxyaniline 2-甲氧基苯胺/邻茴香胺 2-氨基苯甲醚 2-Methoxybenzenamine o-Aminomethoxybenzene o-Methoxyphenylamine 2-methoxy-benzenamine 2-甲氧基苯胺鄰-甲氧苯胺 2-AMINOANISOLE 1-Amino-2-methoxybenzene O-METHOXYANILINE 2-氨基苯甲醚 2-甲氧基苯胺 o-Anisidine O-AMINOANISOLE 原亚锑酸盐 A-ESTER VINYL SULPHONE 1-AMINO-2-METHOXYBENZENE 1-Amino-2-methoxybenzene; 2-Aminoanisole; 2-Methoxyaniline 2-methoxy-aniline 2-Methoxyaminobenzol 邻甲氧基苯胺 O-ANISIDINE Benzenamine, 2-methoxy- 2-Aminoanisole 2-Methoxyaniline
PubChem Substance ID	7000
EC Number	201-963-1
Beilstein Registry Number	386210
Reaxys-RN	386210
Merck Number	667
Chemical Name Translation	邻甲氧基苯胺
LabNetwork Molecule ID	LN00173828
InChI	InChI=1S/C7H9NO/c1-9-7-5-3-2-4-6(7)8/h2-5H,8H2,1H3

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分类

{SNA} A,
A, A-B, AM to AQ, Alpha Sort, Alphabetic, Amines, Analytical Standards, Analytical/Chromatography, Aromatics, Aryl Amines MAK III, Category 2, Chemical Class, Chromatography, Environmental Standards, Food & Beverage Standards, Food Dyes, Food Residue Analysis, Method Specific, Oeko-Tex Standard 100, Volatiles/ Semivolatiles
{SNA} A-B, A-C, Additional Standards, All alphabetical sorted, Alpha Sort, Amines, Analytical Standards,
{SNA} Amines,

产品应用

显微微晶分析检验氰化物。络合指示剂滴定汞。有机合成。

安全信息

Warnings 危化品目录(2015) IRRITANT

GHS Symbol

WGK Germany3

Hazard statements

H301+H311+H331
H350 May cause cancer 可能致癌
H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
H331 Toxic if inhaled 吸入中毒
H311 Toxic in contact with skin 皮肤接触中毒
H301 Toxic if swallowed 吞食有毒

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes T T,Xi

RTECSBZ5410000

Precautionary statements

P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P308+P313
P332+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....
P302+P350
P337+P313
P403+P233
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P201 Obtain special instructions before use. 使用前获取专门指示。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P301+P310+P330
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P304+P340+P311
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P273 Avoid release to the environment. 避免释放到环境中。
P305+P351+P338+P337+P313
P308+P311
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。

Signal word

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；

Risk Statements

R45 May cause cancer 可能致癌
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

UN Number

Storage condition Refrigerator 储存温度2-8°C,充氩保存储存温度2-8℃ 密封避光保存。 Light Sensitive 0-10°C 0-10

Packing GroupIII

Hazard Class6.1

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 870 mg/kg
TOXIC EFFECTS :
   Kidney, Ureter, Bladder - other changes
   Blood - normocytic anemia
   Blood - other changes
REFERENCE :
   IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
   to Man.  (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210)
   V.1-    1972-  Volume(issue)/page/year: 27,63,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 422 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1400 mg/kg
TOXIC EFFECTS :
   Kidney, Ureter, Bladder - other changes
   Blood - normocytic anemia
   Blood - other changes
REFERENCE :
   IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
   to Man.  (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210)
   V.1-    1972-  Volume(issue)/page/year: 27,63,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TLSMA6 Trudy Leningradskogo Sanitarno-Gigienicheskogo Meditsinskogo
   Instituta.  (Leningrad, Russia) V.1-145, 1949-82.  Discontinued.

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 690 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 412,155,1998

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 1200 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
   to Man.  (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210)
   V.1-    1972-  Volume(issue)/page/year: 27,63,1982

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 1250 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/pag

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 38 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 2 mmol/L
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1

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其他信息

职业标准:TW
{
毒性分级:中毒
{Chemical
MSDS 信息:邻甲氧基苯胺(90-04-0).msds
MOL 文件:90-04-0.mol
Sigma Aldrich:90-04-0(si
Acros Organics:邻氨基苯甲醚 o-Anisidine, 99+%(90-04-0)
检测方法:GC,NMR
{Chemicalb
露置空气中变成棕色。能随水蒸气挥发。溶于稀
敏感性:Light Sensitive
用途四:显微微晶分析检验氰化物。络合指示剂滴定汞。有机合成。
Alfa Aesar:邻茴香胺,99% o-Anisidine, 99%(90-04-0)
方法一:由邻硝基苯甲醚还原而得，邻硝基苯甲醚可由邻硝基氯甲苯氧基化得到[91-23-6]，还原剂可采用硫化钠或铁粉。另外，也可由邻硝基苯酚经甲基化、还原来制取邻甲氧基苯胺。原料消耗定额：邻硝基氯苯1301kg/t、甲醇（98%）395kg/t、硫化钠（60%）1128kg/t、烧碱（96%）457kg/t。
能随水蒸气挥发。溶于稀矿酸、乙醇和乙醚、丙酮、苯，微溶于水。有毒。有致癌可能性。有刺激
用途三:可用于制取偶氮染料、冰染染料及色酚AS-OL等染料以及愈创木酚、安痢平等医药。还可制取香兰素等。
职业标准:TWA 0
下游产品:香兰素 --> 愈创木酚 --> 4,8-二羟基喹啉-2-甲酸 --> 萘酚AS-BI磷酸盐 --> 5-溴-8-甲氧基-2-甲基喹啉 --> 2-甲氧基-4-硝基苯胺 --> 2-甲氧基苯硫酚 --> 耐晒猩红RC --> 邻甲氧基-N-乙酰乙酰苯胺 --> 2-乙酰氨基苯甲醚 --> 1-(2-甲氧苯基)哌嗪 --> 1-(2-甲氧基苯基)哌嗪氢溴酸盐 --> 3,4-二氢-8-羟基-4-羰基喹啉-3-羧酸 --> 分散橙 29 --> 2'-甲基乙酰乙酰苯胺 --> N-(4-氨基-2-甲氧基苯基)乙酰胺 --> 3-羟基-N-(2-甲氧基苯基)-2-萘甲酰胺 --> 3,8-二甲基-1,10-菲罗啉 --> 4-羟基-8-甲氧基喹啉-3-羧酸 --> 4-氯-2-氨基苯甲醚 --> 2-氟苯甲醚 --> 天狼黄 --> 直接耐晒黄 G --> 红色基 ITR --> 2-甲氧基苯基异氰酸酯 --> 4-羟基-8-甲氧基喹啉-3-羧酸乙酯 --> 2-甲氧基-4-硝基乙酰苯胺 --> 活性黄KE-4RN --> 耐晒红B盐 --> 直接铜盐灰 GRL --> 2-甲氧基氰苯 --> 桃红色基ITR --> 色酚 AS-CA
用途一:用作染料、香料及医药中间体
用途二:用作测定汞的络合指示剂，偶氮染料中间体及杀菌剂
上游原料:氢氧化钠 --> 甲醇 --> 铁粉 --> 硫化钠 --> 邻氯硝基苯 --> 2-硝基苯酚
图谱信息:邻甲氧基苯胺(90-04-0)质谱(MS) 邻甲氧基苯胺(90-04-0)红外图谱(IR2) 邻甲氧基苯胺(90-04-0)核磁图( 1 HNMR) 邻甲氧基苯胺(90-04-0)核磁图( 13 CNMR) 邻甲氧基苯胺(90-04-0)红外图谱(IR1)
急性毒性:口服-大鼠 LD50: 2000 毫克/公斤; 口服-小鼠 LD50: 1400 毫克/公斤
外观性质:浅黄色油状液体。
储运特性:库房通风低温干燥; 与食品原料分开储运
TCI Shanghai:2-甲氧基苯胺 o-Anisidine,>;98.0%(GC)(T)(90-04-0)
邻甲氧基苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80080580 邻甲氧基苯胺 50ml 38元 2011/08/23 80080526 邻甲氧基苯胺 100ml 72元 2011/04/16 A0486 邻茴香胺 o-Anisidine 500ML 632元