Chlorodiphenylphosphine 二苯基氯化膦
CAS 1079-66-9 MFCD00000529
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors
产品应用
- 合成中锂化反应引入二苯基磷。
相关文献及参考
- Short: EINECS
- Short: III/20b
- Beilstein:16,763
- Reacts with Li metal in liquid ammonia to give the Li diphenylphosphide: Tetrahedron Lett., 21, 3535 (1980). Reaction with vinyl lithium intermediates from the reaction of alkyllithiums with sulfonylhydrazones (see p-Toluenesulfonyl hydrazide, A13529) gives vinylphosphines: Tetrahedron Lett., 22, 4619 (1981).
安全信息
GHS Symbol
- S8 Keep container dry 保持容器干燥;
- S30 Never add water to this product 切勿将水加入该产品中;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S25 Avoid contact with eyes 避免眼睛接触;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S20 When using do not eat or drink 使用时,不得进食,饮水;
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- R14 Reacts violently with water 遇水会猛烈反应
- R22 Harmful if swallowed 吞咽有害
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P301+P317
- P301+P330+P331
- P301+P330+P331+P310
- P302+P361+P354
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P305+P354+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P316
- P317
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
- P404 Store in a closed container. 贮存于密闭容器中。
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H290 May be corrosive to metals 可能腐蚀金属。
- H302 Harmful if swallowed 吞食有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H318 Causes serious eye damage 严重伤害眼睛
- H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
其他信息
- 图谱信息:二苯基氯化膦(1079-66-9)红外图谱(IR1) 二苯基氯化膦(1079-66-9)质谱(MS) 二苯基氯化膦(1079-66-9)核磁图( 13 CNMR) 二苯基氯化膦(1079-66-9)核磁图( 1 HNMR)
- 海关编码:29310095
- Sigma Aldrich:1079-66-9(sigmaaldrich)
- 检测方法:GC
- 外观性质:无色透明液体。 折光率n20/D:1.636沸点:320 °C密度:1.229 闪点:112 °C
- F:1-9-19
- 敏感性:Air & Moisture Sensitive
- Alfa Aesar:二苯基氯化膦,98+% Chlorodiphenylphosphine, 98+%(1079-66-9)
- MOL 文件:1079-66-9.mol
- 蒸气密度:7.8 (vs air)
- 用途一:合成中锂化反应引入二苯基磷。
- 二苯基氯化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0597 二苯基氯化膦 Chlorodiphenylphosphine 25G 205元 2014/06/02 C0597 二苯基氯化膦 Chlorodiphenylphosphine 500G 1800元 2010/06/21 109130250 二苯基氯化膦 Chlorodiphenylphosphine 95%, tech. 25 ML 663元
- TCI Shanghai:二苯基氯化膦 Chlorodiphenylphosphine,>;97.0%(T)(1079-66-9)
- 下游产品:二苯基膦 --> 1,1'-双(二苯基膦)二茂铁 --> 4,5-双二苯基膦-9,9-二甲基氧杂蒽 --> (R)-(-)-1-[(S)-2-二苯基磷二茂铁乙基-二叔丁基磷 --> 双(2-二苯基磷苯基)醚
- Acros Organics:二苯基氯化膦 Chlorodiphenylphosphine, tech., 95%(1079-66-9)
- MSDS 信息:Chlorodiphenylphosphine(1079-66-9).msds
- TSCA:Yes