Acetylferrocene 乙酰基二茂铁
CAS 1271-55-2 MFCD00001432
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {uni_hamburg} no charge; metal-organic; other heterocycle; carbocycle; alicycle; fused rings; 3ring; 4ring; 5ring; 6ring; ketone; 1fragment; zwitterion
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron Catalysts
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron
相关文献及参考
- Short: III/35D5
- Short: EINECS
- A procedure for the conversion of methyl ketones to terminal acetylenes is exemplified by reaction with POCl3 - DMF to give (2-formyl-1-chlorovinyl)ferrocene which, by elimination with NaOH, affords ethynylferrocene: J. Organomet. Chem., 6, 173 (1966); Org. Synth. Coll., 9, 411 (1998).
安全信息
GHS Symbol
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S20 When using do not eat or drink 使用时,不得进食,饮水;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S27/28
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S1 Keep locked up 上锁;
- R24 Toxic in contact with skin 与皮肤接触有毒
- R28 Very toxic if swallowed 吞咽极毒
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P301+P310
- P301+P310+P330
- P305+P351+P338
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H300 Fatal if swallowed 吞食致命
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 25 mg/kg TOXIC EFFECTS : Behavioral - tremor Gastrointestinal - changes in structure or function of salivary glands Skin and Appendages - hair REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570920
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 75 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#08812
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 25 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Vascular - regional or general arteriolar or venous dilation Lungs, Thorax, or Respiration - dyspnea REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570920
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Ocular SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 30 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.
其他信息
- 可燃性危险特性:可燃; 加热分解释放刺激烟雾
- 海关编码:29310095
- F:10
- 毒性分级:高毒
- Acros Organics:乙酰基二茂铁 Acetylferrocene, 95%(1271-55-2)
- MSDS 信息:(Acetylcyclopentadienyl)cyclopentadienyliron(1271-55-2).msds
- Alfa Aesar:1-乙酰基二茂铁,97% 1-Acetylferrocene, 97%(1271-55-2)
- 乙酰基二茂铁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0775 乙酰基二茂铁 Acetylferrocene 10G 240元 2014/06/02 A0775 乙酰基二茂铁 Acetylferrocene 25G 560元 2010/06/21 147990250 乙酰基二茂铁 Acetylferrocene 95% 25 GR 1156元
- 下游产品:二茂铁乙炔 --> 乙烯基二茂铁 --> 乙基二茂铁
- MOL 文件:1271-55-2.mol
- 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
- 不溶于水,溶于乙醇。
- 储运特性:库房通风低温干燥
- Sigma Aldrich:1271-55-2(sigmaaldrich)
- 急性毒性:口服- 大鼠 LDL0: 5 毫克/ 公斤; 静脉-小鼠 LD50:75 毫克/公斤
- 图谱信息:乙酰基二茂铁(1271-55-2)核磁图( 1 HNMR) 乙酰基二茂铁(1271-55-2)质谱(MS) 乙酰基二茂铁(1271-55-2)核磁图( 13 CNMR) 乙酰基二茂铁(1271-55-2)红外图谱(IR2) 乙酰基二茂铁(1271-55-2)红外图谱(IR1)
- 类别:易燃物品