Bismuth(III) Chloride 氯化铋(III)

CAS 7787-60-2 MFCD00003461

化学结构图

7787-60-2
SMILES:

化学属性

TSCAYes
SolubilitySoluble in HCl, HNO3, acetone, ethyl acetate. Insoluble in alcohol. Decomposed by water to BiOCl
Flash Point430°C
Mol. FormulaBiCl3
Mol. Weight315.34
Density4.75
Appearance white xtl.
Stabilitymoisture sensitive
Boiling Point447 °C at 760 mmHg
Melting Point230-232 °C

别名和识别编码

Chemical NameBismuth(III) Chloride
Synonym Bismuth chloride {LY} Bismuth chloride {} {LY} Bismuth chloride {} {} {LY} Bismuth chloride {} {} {} {LY} Bismuth chloride {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bismuth chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87561573
EC Number232-123-2
Merck Number1262
Beilstein Registry Number2384789
Chemical Name Translation氯化铋(III)
Reaxys-RN3903092
LabNetwork Molecule IDLN00196712
MDL NumberMFCD00003461
CAS Number7787-60-2
Canonical SMILESCl[Bi](Cl)Cl
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分类

  • {SNA} Bismuth Catalysts, Bismuth Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, 材料科学
  • {SNA} 83: Bi, Beaded Materials, Bi, Bismuth, Bismuth Catalysts

产品应用

  • 制造铋盐,有机反应催化剂,高纯材料。

相关文献及参考

  • For catalysis of Diels-Alder and hetero Diels-Alder reactions, see: J. Org. Chem., 62, 4880 (1997); Tetrahedron Lett., 39, 1161 (1998).
  • Short: II/25A
  • Catalyzes the addition of 1,3-dicarbonyl compounds to Michael acceptors under solvent-free conditions with microwave irradiation: Tetrahedron Lett., 38, 1449 (1997).
  • Merck: 14,1262
  • Lewis acid catalyst which promotes the rearrangement of acetanilides to o-amino ketones: Tetrahedron Lett., 3217 (1976).
  • For a brief feature on Bi(III) catalysts, see: Synlett, 1194 (2001). For a review of their use in acylation and sulfonylation reactions, see: Synlett, 181 (2002).
  • Promotes the chemoselective deprotection of N-Boc amino acids and peptides: Tetrahedron Lett., 47, 389 (2006).
  • Silyl enol ethers can be ɑ-acylated with acyl chlorides in the presence of a catalytic amount of BiCl3 and NaI or ZnI2; other Lewis acids such as ZnCl2 were less effective: J. Org. Chem., 61, 3885 (1996).
  • Arenes undergo sufonylation by heating with arenesulfonyl chlorides in the presence of BiCl3 (5 mol%) and triflic acid (10 mol%) to give high yields of mixed diaryl sulfones; neither BiCl3 nor TfOH alone is effective: Tetrahedron Lett., 40, 9233 (1999).

安全信息

GHS Symbol
WGK Germany2
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H303 May be harmfully swallowed 吞食可能有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSEB2690000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P332+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S3 Keep in a cool place 保存在阴凉处;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
UN Number 3260 UN3260
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store
Packing GroupIII
Hazard Class8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3334 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(6),16,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(6),16,1986

其他信息

  • Acros Organics:氯化铋 Bismuth(III) chloride, anhydrous, 98+%(7787-60-2)
  • 下游产品:氯乙烷
  • 用途一:用作分析试剂及催化剂,也用于铋盐制取
  • MOL 文件:7787-60-2.mol
  • 有氯化氢气味,具溶解性。加热则挥发,约在430℃时升华。在水中分解成氧氯化铋,能溶于盐酸、硝酸、无水乙醇、丙酮和乙酸乙酯。
  • 图谱信息:氯化铋(7787-60-2)红外图谱(IR1)
  • 升华点:430 °C
  • Sigma Aldrich:7787-60-2(sigmaaldrich)
  • Alfa Aesar:氯化铋,98% Bismuth(III) chloride, 98% (dry wt.), may cont. up to 3% water(7787-60-2)
  • 用途二:制造铋盐,有机反应催化剂,高纯材料。
  • MSDS 信息:Bismuth trichloride (7787-60-2).msds
  • 氯化铋价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 20008816 氯化铋 100g 43元 2010/06/21 208835000 氯化铋 Bismuth(III) chloride 98+%, anhydrous 500 GR 6703元 2010/06/21 208830250 氯化铋 Bismuth(III) chloride 98+%, anhydrous 25 GR 660元
  • 敏感性:Hygroscopic

系列性分类


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