Tricyclohexyl phosphine 三环己基膦
CAS 2622-14-2 MFCD00003853
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分类
- {SNA} Catalysis, Basic Phosphine Ligands, Catalysis and Inorganic Chemistry,
- {SNA} Basic Phosphine Ligands, Buchwald Ligands and Complexes, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Development Quantities for Research, Phosphine Compounds, Phosphine Ligands, Related Palladacycles
- {SNA} Related Palladacycles, Basic Phosphine Ligands, Buchwald Ligands and Complexes, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Development Quantities for Research, Phosphine Compounds, Phosphine Ligands
- {SNA} Basic Phosphine Lig
- {SNA} Basic Phosphine Ligands, Catalysis and Inorganic Chemistry,
产品应用
- 金属催化剂。
相关文献及参考
- Beilstein: 16,IV,947
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R22 Harmful if swallowed 吞咽有害
- R11 Highly flammable 非常易燃
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R48/20
- R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
- R36 Irritating to eyes 刺激眼睛
- P301+P312
- P305+P351+P338
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- H315 Causes skin irritation 会刺激皮肤
- H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
- H319 Causes serious eye irritation 严重刺激眼睛
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H335+H336
- H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H351 Suspected of causing cancer 怀疑致癌
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
其他信息
- 存储注意事项:空气敏感;氮气保护
- Alfa Aesar:三环己基膦,96% Tricyclohexylphosphine, 96%(2622-14-2)
- TCI Shanghai:三环己基膦(约18%的甲苯溶液,约0.60mol/L)(含三环己基氧化膦) Tricyclohexylphosphine (contains Tricyclohexylphosphine Oxide) (ca. 18% in Toluene, ca. 0.60mol/L)(2622-14-2)
- 敏感性:Air Sensitive
- 下游产品:二氯二(三环己基瞵)钯
- 上游原料:乙醚 --> 氯化铵 --> 镁 --> 三氯化磷 --> 溴代环己烷
- MOL 文件:2622-14-2.mol
- Acros Organics:三环己基膦 Tricyclohexyl phosphine, 97%(2622-14-2)
- 三环己基膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A26197103 三环己基膦 25g 2860元 2010/06/21 421610010 三环己基膦 Tricyclohexylphosphine 97% 1 GR 363元 2010/06/21 421610050 三环己基膦 Tricyclohexylphosphine 97% 5 GR 1622元
- 图谱信息:三环己基膦(2622-14-2)质谱(MS) 三环己基膦(2622-14-2)核磁图( 13 CNMR)
- 用途一:作为配体,用于Buchwald, Suzuki等偶联反应中
- 用途二:金属催化剂。
- Sigma Aldrich:2622-14-2(sigmaaldrich)
- MSDS 信息:Tricyclohexyl phosphine(2622-14-2).msds