2-Methyl-3-butyn-2-ol 2-甲基-3-丁炔-2-醇
CAS 115-19-5 MFCD00004467
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
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分类
- Alkynes, Building Blocks, Chemical Synthesis, Organic Building Blocks, Terminal
- {uni_hamburg} no charge; alcohol; 1fragment
- {SNA} Alkynes, Building Blocks, Chemical Synthesis, Organic Building Blocks, Terminal
相关文献及参考
- Alternatively, the protecting group can be removed from the intermediate by base to give monoarylacetylenes: J. Org. Chem., 48, 5135 (1983); 57, 6998 (1992). For an improved procedure, see: Synthesis, 589 (1996).
- Adduct of acetylene and acetone which acts as an acetylene equivalent in the Pd-catalyzed (Sonogashira) coupling reaction with aryl or heteroaryl halides, permitting a one-pot diarylation by different halides: Synthesis, 571 (1984):
- Short: III/38B
- Merck:14,6034
- Short: IV/18B
- Merck:14,6034 Beilstein:1(1)235
安全信息
GHS Symbol




- H226 Flammable liquid and vapour 易燃液体和蒸气
- H351 Suspected of causing cancer 怀疑致癌
- H318 Causes serious eye damage 严重伤害眼睛
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H302 Harmful if swallowed 吞食有害
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312+P330
- P303+P361+P353
- P304+
- P305+P351+P338
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护;
- S39 Wear eye/face protection 戴眼睛/面孔保护装置;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- R10 Flammable 易燃
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 500 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - ataxia Lungs, Thorax, or Respiration - other changes REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 31(4),55,1987
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1161 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold REFERENCE : YKKZAJ Yakugaku Zasshi. Journal of Pharmacy. (Nippon Yakugakkai, 2-12-15 Shibuya, Shibuya-ku, Tokyo 150, Japan) No.1- 1881- Volume(issue)/page/year: 76,181,1956
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 2 gm/m3 TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - ataxia Lungs, Thorax, or Respiration - other changes REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 31(4),55,1987
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1950 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than
其他信息
- TCI Shanghai:2-甲基-3-丁炔-2-醇 3-Methyl-1-butyn-3-ol (=2-Methyl-3-butyn-2-ol),>;98.0%(GC)(115-19-5)
- 毒性分级:中毒
- 和水混溶,和丙酮、苯、溶纤剂、四氯化碳、环己烷、乙二醇、乙酸乙酯、煤油、甲基乙基酮、矿物醇、一乙醇胺、渣滓油、石油醚、豆油、斯托达德溶液混溶。
- 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
- MOL 文件:115-19-5.mol
- 用途一:用作合成医药、农药、萜烯类香料的中间体,酸蚀抑制剂、粘度稳定剂、减粘剂等
- 检测方法:GC,NMR
- Alfa Aesar:2-甲基-3-丁炔-2-醇,98% 2-Methyl-3-butyn-2-ol, 98%(115-19-5)
- 类别:易燃液体
- MSDS 信息:2-甲基-3-丁炔-2-醇(115-19-5).msds
- 海关编码:29052990
- 上游原料:丙酮 --> 乙炔
- 外观性质:无色、有芳香气味的液体。
- Acros Organics:2-甲基-3-丁炔-2-醇 2-Methyl-3-butyn-2-ol, 98%(115-19-5)
- 3-甲基丁炔醇-3价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0180 3-甲基-1-丁炔-3-醇(=2-甲基-3-丁炔-2-醇) 3-Methyl-1-butyn-3-ol (=2-Methyl-3-butyn-2-ol) 500ML 384元 2014/06/02 M0180 3-甲基-1-丁炔-3-醇(=2-甲基-3-丁炔-2-醇) 3-Methyl-1-butyn-3-ol (=2-Methyl-3-butyn-2-ol) 25ML 118元 2010/06/21 156820010 3-甲基丁炔醇-3 2-Methyl-3-butyn-2-ol 98% 1 LT 753元
- 下游产品:2-甲基-2-丁醇 --> 2,5-二甲基-2,5-己二醇
- 蒸气压:15 mm Hg ( 20 °C)
- 图谱信息:3-甲基丁炔醇-3(115-19-5)红外图谱(IR1) 3-甲基丁炔醇-3(115-19-5)红外图谱(IR2) 3-甲基丁炔醇-3(115-19-5)核磁图( 1 HNMR) 3-甲基丁炔醇-3(115-19-5)Raman光谱 3-甲基丁炔醇-3(115-19-5)质谱(MS) 3-甲基丁炔醇-3(115-19-5)核磁图( 13 CNMR)
- 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
- 急性毒性:口服- 大鼠 LD50: 1950 毫克/ 公斤; 口服- 小鼠 LD50: 500 毫克/ 公斤
- Sigma Aldrich:115-19-5(sigmaaldrich)
- 可燃性危险特性:遇明火、高温、氧化剂易燃; 遇热分解有毒刺激烟雾