1-Heptanethiol 1-庚硫醇

CAS 1639-09-4 MFCD00004911

化学结构图

1639-09-4
SMILES: CCCCCCCS

化学属性

Mol. FormulaC7H16S
Mol. Weight132
Density0.844
Refractive index1.4500 to 1.4530
Boiling Point173-176
Flash Point46°C(lit.)
TSCAYes
Melting Point-43°
Solubility不溶于水,易溶于醇、醚。
Stability对空气敏感

别名和识别编码

Chemical Name1-Heptanethiol
Synonym 1-HEPTANETHIOL,97% 1-HEPTYL MERCAPTAN 1-Heptyl mercaptan 1-Heptylmercaptan 1-heptanethiol 1-mercaptoheptane 1-庚烷硫醇 1-庚硫醇 Heptan-1-thiol Heptanethiol Heptyl mercaptan Mercaptan C7 Heptyl mercaptan, Mer Heptyl mercaptan, Mercaptan C7 MERCAPTAN C7 Mercaptan C7 N-HEPTYL MERCAPTAN N-heptyl mercaptan Normal-heptyl mercaptan USAF EK-2122 USAF ek-2122 Usaf ek-2122 heptanethiol(non-specificname) heptylmercaptan(non-specificname) heptylmercaptannormal n-Heptanethiol n-Heptyl mercaptan n-Heptylthiol n-heptanethiol n-heptylmercaptan n-heptylthiol usafek-2122 {} {
CAS Number1639-09-4
EC Number216-678-8
Beilstein Registry Number1731687
MDL NumberMFCD00004911
PubChem Substance ID87570486
Reaxys-RN1731687
Chemical Name Translation1-庚硫醇
Wiswesser Line NotationSH7
LabNetwork Molecule IDLN00162815
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分类

  • Alkyl Thiols, Materials Science, Micro/NanoElectronics, Self Assembly & Contact Printing, Self-Assembly Materials, Thiols
  • {SNA} Alphabetical Listings, Flavors and Fragrances, G-H
  • {SNA} Alkyl Thiols, Micro/NanoElectronics, Self Assembly & Contact Printing, Self-Assembly Materials, Thiols, 材料科学
  • {SNA} Alkyl Thiols, Materials Science, Micro/NanoElectronics, Self Assembly & Contact Printing, Self-Assembly Materials,
  • {SNA} Alkyl Thiols, Micro/NanoElectronics, Self Assembly and Lithography, Self-Assembly Materials, Thiols, 材料科学
  • {SA} Alkyl Thiols, Materials

相关文献及参考

  • Beilstein:1,415
  • Short: IV/18B
  • Short: IV/16
  • Short: IV/20A
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSMJ1400000
Signal word Warning
UN Number 3336 UN 3336 3/PG 3 UN3336
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Air Sensitive
Packing GroupIII
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Hazard Codes 3
Hazard Class3
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

其他信息

  • 灭火剂:干粉、干砂、二氧化碳、泡沫
  • 下游产品:
  • TCI Shanghai:1-庚硫醇 1-Heptanethiol,>;96.0%(GC)(1639-09-4)
  • MSDS 信息:庚硫醇(1639-09-4).msds
  • Sigma Aldrich:1639-09-4(sigmaaldrich)
  • 敏感性:Air Sensitive
  • F:9-13-23
  • 海关编码:29309070
  • 毒性分级:中毒
  • 类别:易燃液体
  • 职业标准:CL AIR 0.5 ppm/15分
  • Alfa Aesar:1-庚硫醇,98% 1-Heptanethiol, 98%(1639-09-4)
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒硫氧化物烟雾; 遇酸、水产生有毒硫化物气体
  • 1-庚硫醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0029 1-庚硫醇 1-Heptanethiol 25G 578元 2014/06/02 H0029 1-庚硫醇 1-Heptanethiol 10G 344元 2010/05/25 L07079 1-庚硫醇, 98% 1-Heptanethiol, 98% 25g 434元
  • MOL 文件:1639-09-4.mol
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • 外观性质:具有强烈臭味的无色液体。
  • 急性毒性:腹腔- 小鼠 LD50: 200 毫克/ 公斤

系列性分类


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